J Agric Food Chem
Departamento Medio Ambiente, INIA, Apartado 8111, 28080 Madrid, Spain.
Published: February 2003
Laboratory studies were undertaken to evaluate the influence of fertilizers on pendimethalin volatilization and persistence in soil. Various organic fertilizers such as liquid humic substances and urea were used at doses of 100 L/ha or 170 kg of N/ha, respectively. Herbicide residues were determined in air, soil solution, and soil samples by GC-ECD; the recovery of pendimethalin from spiked fertilized or control samples was found to be 81-103%. Liquid humic fertilizers increased pendimethalin dissipation during the first part of the assay, although 4 months after application, herbicide levels were similar to those observed in unfertilized soil. Fertilization of soil with urea decreased, in general, pendimethalin volatilization but increased herbicide levels in soil solution and persistence in soil, with a pendimethalin half-life approximately 70% higher than that found in unfertilized soil.
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http://dx.doi.org/10.1021/jf0205561 | DOI Listing |
Sci Total Environ
November 2024
Aix Marseille Univ, CNRS, LCE, Marseille, France.
The currently used pesticides are mostly semi-volatile organic compounds. As a result, a fraction of them can be adsorbed on atmospheric aerosol surface. Their atmospheric photolysis is poorly documented, and gaps persist in understanding their reactivity in the particle phase.
View Article and Find Full Text PDFEnviron Pollut
March 2024
Aix Marseille Univ, CNRS, LCE, Marseille, France. Electronic address:
Pesticides in the atmosphere can exist in both gaseous and particulate phases due to their semi-volatile properties. They can undergo degradation when exposed to atmospheric oxidants like ozone and hydroxyl radicals. The majority of studies on the atmospheric reactivity of pesticides study them in combination, without considering potential mixture effects that could induce uncertainties in the results.
View Article and Find Full Text PDFJ Toxicol Environ Health A
March 2023
School of Earth, Environmental, and Marine Sciences, University of Texas Rio Grande Valley, Brownsville, TX, USA.
The synergy between multiple compounds and other stressors, including heat, creates volatility and greater unpredictability than standard single-chemical toxicity testing, especially in the case of pesticides and metabolites which might contain several noxious ingredients resulting in adverse ecological effects. To address this, the aim of this study was to examine the dose- and time-dependent effects of low- and high-dose pesticide mixture (metalachlor, linuron, isoproturon, tebucanazole, aclonifen, atrazine, pendimethalin, azinphos-methyl) and heat stress co-exposure (22°C control/32°C treatment for 4-week) on free-swimming behaviors and cumulative actionless time (CAT) of goldfish. Behavioral analysis showed a dose- and time-dependent decrease in distance swam, as well as a subsequent increase in CAT.
View Article and Find Full Text PDFSci Total Environ
September 2022
University of Natural Resources and Life Sciences Vienna (BOKU), Department of Integrative Biology and Biodiversity Research, Institute of Zoology, Gregor Mendel Straße 33, 1180 Vienna, Austria.
Little is known about (i) how numbers and concentrations of airborne pesticide residues are influenced by land use, interactions with meteorological parameters, or by substance-specific chemo-physical properties, and (ii) what potential toxicological hazards this could pose to non-target organisms including humans. We installed passive air samplers (polyurethane PUF and polyester PEF filter matrices) in 15 regions with different land uses in eastern Austria for up to 8 months. Samples were analyzed for 566 substances by gas-chromatography/mass-spectrometry.
View Article and Find Full Text PDFPest Manag Sci
February 2020
Department of Plant and Soil Sciences, Mississippi State University, Mississippi State, MS, USA.
Background: Unlike post-emergence herbicides (POSTs), little is known about droplet size effect on pre-emergence herbicide (PRE) efficacy. Four nozzle types were used to apply different PRE herbicides on eight soybean fields in Missouri and Mississippi in 2017 and 2018, respectively. Pendimethalin, metribuzin, clomazone, imazethapyr and pyroxasulfone were selected based on their physicochemical characteristics (adsorption, volatility and solubility) and were sprayed using XR11002, ULD12002, TTI6011002, and TTI11002 nozzles.
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