Experiments have been devised to study the rate of ingrowth of bone into porous metal with pore sizes up to 100 mu and to study the significance of a gap between the porous metal surface and bone. When the porous coat was in direct apposition with bone, the implant was firmly locked in place after a three week period and the plateau value of implant-tissue shear strength was reached at four weeks. A gap of 1.5 mm between the bone and the implant was bridged by new bone within four weeks.
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http://dx.doi.org/10.1002/jbm.820100210 | DOI Listing |
Talanta
January 2025
School of Pharmaceutical Sciences, Key Laboratory of Innovative Drug Development and Evaluation, Hebei Medical University, Shijiazhuang, 050017, China. Electronic address:
Tanshinol, an active ingredient extracted from the Salvia miltiorrhiza herb, is widely used in Chinese medicine or health supplements. Accurately and rapidly quantifying of tanshinol under near-neutral or neutral conditions is of great significance but still a significant challenge. Herein, a novel electrochemical sensor based on bimetallic FeCo phosphides (FeCoP) was developed for rapid and sensitive detection of tanshinol in near-neutral environments.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
School of Materials Science and Engineering, Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, PR China. Electronic address:
The development of earth-abundant oxygen evolution reaction (OER) electrocatalysts with high activity and durability is critical for replacing noble-metal-based catalysts in the applications of scalable water electrolysis. A freestanding electrode architecture offers significant advantages over conventional coated powder forms due to enhanced kinetics and stability. However, precise control over electrode composition and the construction of uniformly distributed active sites within these electrodes remain challenging.
View Article and Find Full Text PDFMikrochim Acta
January 2025
Indian Institute of Technology (BHU), Varanasi, 221005, India.
In the modern age, half of the population is facing various chronic illnesses due to glucose maintenance in the body, major causes of fatality and inefficiency. The early identification of glucose plays a crucial role in medical treatment and the food industry, particularly in diabetes diagnosis. In the past few years, non-enzymatic electrochemical glucose sensors have received a lot of interest for their ability to identify glucose levels accurately.
View Article and Find Full Text PDFACS Nano
January 2025
Creative Research Initiative Center for Nanospace-confined Chemical Reactions (NCCR), Pohang University of Science and Technology (POSTECH), Pohang 37673, Korea.
Unlike homogeneous metal complexes, achieving absolute control over reaction selectivity in heterogeneous catalysts remains a formidable challenge due to the unguided molecular adsorption/desorption on metal-surface sites. Conventional organic surface modifiers or ligands and rigid inorganic and metal-organic porous shells are not fully effective. Here, we introduce the concept of "ligand-porous shell cooperativity" to desirably reaction selectivity in heterogeneous catalysis.
View Article and Find Full Text PDFChemSusChem
January 2025
Indian Institute of Technology Ropar, Chemistry, Nangal Road, 140001, Rupnagar, INDIA.
Photocatalytic conversion of CO2 into value-added chemicals offers a propitious alternative to traditional thermal methods, contributing to environmental remediation and energy sustainability. In this respect, covalent organic frameworks (COFs), are crystalline porous materials showcasing remarkable efficacy in CO2 fixation facilitated by visible light owing to their excellent photochemical properties. Herein, we employed Lewis acidic Zn(II) anchored pyrene-based COF (Zn(II)@Pybp-COF) to facilitate the photocatalytic CO2 utilization and transformation to 2-oxazolidinones.
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