The delithiation process in monoclinic Li3V2(PO4)3 has been determined by powder neutron diffraction coupled with 7Li solid-state NMR techniques. Charge ordering of vanadium (V3+/V4+) was observed in Li2V2(PO4)3 as shown by the gray and blue V-O octahedra, respectively, indicating that the electrons are pinned in this phase and hence transport is limited.
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| http://dx.doi.org/10.1021/ja028973h | DOI Listing |
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