We present an experimental and theoretical study of piles consisting of monodisperse spherical grains mixed with a weight fraction nu(d) of dimer grains made by the rigid bonding of two such spherical grains. The maximum static angle of stability tantheta(c) of the pile increases from 0.45 to 1.1 and the grain packing fraction Phi decreases from 0.58 to 0.52 as nu(d) is increased from 0 to 1. The stability of these piles appears to be controlled by the grains sitting on the surface, which roll out of their local "traps" as the tilt angle is increased. We attribute the increase in tan theta(c)(nu(d)) to the enhanced stability of dimers on the surface, such that at higher tilt angles, there are sufficiently many stable surface traps available to accommodate the reduced density of monomers on the surface. A full characterization of the grain-scale roughness of the surface is required to quantitatively account for the changes in theta(c) with nu(d).
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http://dx.doi.org/10.1103/PhysRevE.66.051307 | DOI Listing |
Langmuir
January 2025
Polymer Science and Engineering Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411008, India.
2,2-Bis-(methylol)propionic acid-based second-generation polyester dendron amphiphile (T-D) containing visible light-responsive donor-acceptor Stenhouse adduct (DASA) as hydrophobic tails is synthesized. Micelles of T-D amphiphile and its mixed micelles of varying compositions with nonresponsive dendron amphiphile containing lauryl groups are prepared in aqueous solution. In transmission electron microscopy and atomic force microscopy analyses, T-D amphiphiles show rice grain-like ellipsoidal micelles as the predominant morphology.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Department of Chemical Engineering, Indian Institute of Technology Gandhinagar, India.
Self-assembly of nanoparticles (NPs) in solution has garnered tremendous attention among researchers because of their electrical, chemical, and optoelectronic properties at the macroscale with potential applications in bio-imaging, bio-medicine, and therapeutics. Control of size, shape, and composition at the nanoscale is important in tuning the material's bulk properties. The grafting of NPs with polymers enables us to tune such bulk material properties at the nano level by controlling their assemblies, especially in solutions.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Grain Science and Industry, Kansas State University, Manhattan, KS 66506, USA. Electronic address:
Starch spherulite is a unique form of resistant starch characterized by a spherical structure with crystalline lamellae that are radially oriented and may find applications in delivery of nutrients and bioactives to the lower gastrointestinal tract. Formation of starch spherulites generally requires heating to a high temperature followed by quenching and long crystallization time. The objectives of this study were to gain a deeper understanding of the factors influencing spherulite formation from pea starch (PS) and high-amylose maize starch (HAMS) and investigate if spherulites could be formed by a slow cooling rate and determine the crystalline structure and morphology of the spherulites formed.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
School of Rare Earth Industry (School of Rare Earth Engineering and Technology), Inner Mongolia University of Science and Technology, Baotou 014010, China.
The changes in the inclusions in 316L stainless steel before and after Ce addition were studied by adding different contents of Ce. The effects of rare earth Ce treatment on the modification of MnS inclusions in steel and the pitting corrosion resistance of 316L stainless steel are studied by field-emission scanning electron microscopy, laser confocal microscopy, the 6% FeCl corrosion weight loss test, and Tafel polarization curve test. The results show that the addition of Ce reduces the corrosion rate of stainless steel in 6% FeCl solution, and reduces the number and size of corrosion pits.
View Article and Find Full Text PDFBMC Cancer
January 2025
Finetech in Medicine Research Center, Iran University of Medical Sciences, Tehran, Iran.
Background And Aim: Zinc oxide and copper oxide nanoparticles are known for their promising biological activities. This study aims to synthesize zinc oxide nanoparticles and copper-doped zinc oxide nanoparticles to harness the combined cytotoxic and anticancer effects of them in vitro and in vivo studies.
Methods: Zinc oxide nanoparticles, both doped and undoped, were synthesized using a chemical co-precipitation method.
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