We show here that field emission (FE) can be used to directly observe the vibration resonances nu(R) of carbon nanotubes (CNTs) and that the tension created by the applied field allows the tuning of these resonances by up to a factor of 10. The resonances are observable by the changes they create in the FE pattern or the emitted FE current. The tuning is shown to be linear in voltage and to follow from the basic physics of stretched strings. The method allows one to study the mechanical properties of individual multiwall carbon nanotubes within an ensemble and follow their evolution as the CNTs are modified. The tuning and detection should be useful for nanometric resonant devices.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1103/PhysRevLett.89.276103 | DOI Listing |
Sci Rep
January 2025
Department of Mechanical and Manufacturing Engineering, Manipal Institute of Technology, Manipal Academy of Higher Education, Manipal, 576104, India.
Vegetable oil-based lubricants, modified through transesterification and epoxidation, present a sustainable alternative to mineral lubricants for transport and industrial use. This study evaluates epoxidized jatropha oil (EJA) enhanced with multi-walled carbon nanotubes (MWCNT) as a bio-lubricant for compression ignition engines. MWCNT, dispersed in EJA using an ultrasonic probe sonicator with Triton X-100 as a surfactant, was tested at nanoparticle concentrations from 0.
View Article and Find Full Text PDFAnal Chim Acta
February 2025
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, Shandong Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science & Technology, Qingdao, 266042, China. Electronic address:
Wearable microneedle array (MNA) based electrochemical sensors have gained increasing attention for their capability to analyze biomarkers in the interstitial fluid (ISF), enabling noninvasive, continuous monitoring of health parameters. However, challenges such as nonspecific adsorption of biomolecules on the sensor surfaces and the risk of infection at the microneedle penetration sites hinder their practical application. Herein, a wearable dual-layer microneedle patch was prepared to overcome these issues by integrating an antimicrobial microneedle layer with an antifouling sensing layer.
View Article and Find Full Text PDFAnal Chim Acta
February 2025
Chemistry Department, Faculty of Science, Ain-Shams University, Cairo, 11566, Egypt; Department of Chemistry, Faculty of Science, Galala University, New Galala City, Suez, Egypt. Electronic address:
Background: Electrochemical methods, particularly those utilizing sensors, offer distinct advantages over classical analytical methods. They are cost-effective, compatible with mass fabrication, suitable for remote sensing, and can be designed as handheld analyzers. In this context, MIL-101(Cr)-(COOH)₂@MWCNTs was utilized for the first time as a modifier for GCE for the sensitive voltammetric detection of Pb(II), Cu(II), and Hg(II).
View Article and Find Full Text PDFChemistry
January 2025
The University of Electro-Communications: Denki Tsushin Daigaku, Department of Engineering Science, JAPAN.
(6,5)-enriched single-walled carbon nanotubes (SWCNTs) were reductively arylated using sodium naphthalenide and monosubstituted and disubstituted iodobenzene derivatives to control their photoluminescence (PL) properties. In the reactions with substituted iodobenzenes, the degree of functionalization was influenced by the substituents on the aryl groups depending on their position, which allowed us to realize control of the PL intensity. The substituents at the 2-position and methyl groups at the 3,5-positions of the phenyl group respectively increased the E11** PL and E11* PL selectivity at ~1230 and ~1100 nm.
View Article and Find Full Text PDFACS Omega
January 2025
Department of Chemical Engineering, Istanbul Technical University, Istanbul 34469, Türkiye.
In this study, a bovine serum albumin (BSA)-coated magnetic single-walled carbon nanotube (mCNT) was synthesized using covalent functionalization. Mitoxantrone (MTO) was chosen as a model drug, and loading/release profiles of mCNTs were evaluated. To synthesize BSA-coated mCNT, 1-ethyl-3-(3-(dimethylamino)propyl) carbodiimide and -hydroxysuccinimide were used as cross-linking agents.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!