Objectives: A range of esthetic restorative dental materials are now available to dental clinicians. The aim of this study was to evaluate the relative fluoride recharge potential of a number of these materials in vitro over two years.
Methods: Disc samples (12 mm x 2 mm) of each of the materials were placed into artificial saliva at neutral pH. The materials tested were: two glass ionomers (Chemfil; Ketac-Fil), two resin-modified glass ionomers (Photac-Fil Aplicap; Vitremer), two compomers (Dyract; Compoglass) and two composites (Heliomolar; Concise). At 13 intervals over a two years period the discs were subjected to a 2 min fluoride recharge by exposure to sodium fluoride (500 ppm F). The pre- and post-recharge fluoride release values were determined using an ion sensitive electrode.
Results: At all time intervals the post-recharge fluoride release of the materials was significantly different (MANOVA p<0.0001). The mean values for post-recharge fluoride release after two years were: Chemfil 10.3, Ketac 3.0, Vitremer 9.0, Photac-Fil Aplicap 12.1, Compoglass 5.0, Dyract 3.6, Concise 0.3, Heliomolar 0.2 (units = microgF/cm(2)/h).
Significance: Esthetic fillings vary significantly in their capacity to absorb and re-release fluoride. The glass ionomer-based materials displayed a far greater potential for fluoride recharge than the composites, in which the recharge was virtually negligible. Whilst it cannot be assumed that fluoride release is directly proportional to cariostatic potential, these results suggest that, where possible, glass ionomer-based materials should be used in patients who have a high caries rate.
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http://dx.doi.org/10.1016/s0109-5641(02)00011-8 | DOI Listing |
Sci Rep
December 2024
Hebei Province Collaborative Innovation Center for Sustainable Utilization of Water Resources and Optimization of Industrial Structure, Hebei GEO University, Shijiazhuang, 050031, China.
Iodine and fluoride are essential trace elements for human health, with both deficiency and excess intake impacting well-being. This study investigates the groundwater funnel area in eastern Hengshui City, utilizing groundwater level and hydrochemical data from 2014 to 2022. Hydrogeochemical methods were employed to comprehensively analyze the evolution characteristics and causes of iodine and fluoride concentrations in the funnel area.
View Article and Find Full Text PDFSmall
November 2024
Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen, 518055, China.
Lithium (Li) metal anode, one of the most promising candidates for next-generation rechargeable batteries, has always suffered from uneven Li deposition/stripping. To address this issue, this work designs a novel nickel-carbon composite modified Li metal anode (FNC-NF) by carbonizing fluoride nickel hydroxide nanosheet arrays grown on nickel foam (NF). These electrochemical tests present that the conductive and lithiophilic FNC can effectively restrain the growth of Li dendrites during the cycling of Li deposition/stripping at large capacities up to 10 mAh cm.
View Article and Find Full Text PDFJ Colloid Interface Sci
October 2023
State Key Laboratory of Separation Membranes and Membrane Processes/National Center for International Joint Research on Separation Membranes, School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China.
Angew Chem Int Ed Engl
October 2024
College of Chemistry, Huazhong Agricultural University, Wuhan, 430070, P. R. China.
Lithium-based rechargeable dual-ion batteries (DIBs) based on graphite anode-cathode combinations have received much attention due to their high resource abundance and low cost. Currently, the practical realization of the batteries is hindered by easy oxidation of the electrolyte at the cathode interface, and solvent co-intercalation at the anode-electrolyte interface. Configuration of a "solvent-in-salt" electrolyte with a high concentration of Li salt is expected to stabilize the electrolyte chemistry versus both electrodes, yet inevitably reduces the mobility of the solvated working ions and increases the cost of the electrolyte.
View Article and Find Full Text PDFAdv Mater
November 2024
State Key Laboratory of High-Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 585 He Shuo Road, Shanghai, 201899, China.
Here, a rechargeable carbon fluoride battery is demonstrated with unprecedented high rate and long life by oxygen doping and electrolyte formulation. The introductions of Mn-O catalyst and porous structure during the oxidation process of CF cathode can promote the splitting of Li-F during charging. By further modulating the electrolyte with triphenylantimony chloride (TSbCl) as anion acceptor and CsF as product modulator, the more readily dissociable CsLiF product instead of LiF is preferentially formed, and the TSbCl-salt protection interface is constructed to confine Li-F based products and reduce fluoride loss at cathode side.
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