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http://dx.doi.org/10.1002/1521-3773(20020315)41:6<962::aid-anie962>3.0.co;2-9 | DOI Listing |
Inorg Chem
January 2025
Hoffmann Institute of Advanced Materials, Shenzhen Polytechnic University, 7098 Liuxian Blvd, Nanshan District, Shenzhen 518055, P. R. China.
Metal-organic frameworks have received extensive development in the past three decades, which are generally constructed via the reaction between inorganic building units and commercially available or presynthesized organic linkers. However, the presynthesis of organic linkers is usually time-consuming and unsustainable due to multiple-step separation and purification. Therefore, methodology development of a new strategy is fundamentally important for the construction and further exploration of the applications of MOFs.
View Article and Find Full Text PDFJ Comput Chem
January 2025
Nantes Université, CNRS, CEISAM UMR 6230, Nantes, France.
Carbonyl complexes of metals with an α-diimine ligand exhibit both emission and ligand-selective photodissociation from MLCT states. Studying this photodissociative mechanism is challenging for experimental approaches due to an ultrafast femtosecond timescale and spectral overlap of multiple photoproducts. The photochemistry of a prototypical system is investigated with non-adiabatic dynamic simulations.
View Article and Find Full Text PDFDiagnostics (Basel)
December 2024
Department of Nuclear Medicine and Molecular Imaging, Institut de Cancérologie de Strasbourg Europe (ICANS), University Hospitals of Strasbourg, University of Strasbourg, 67200 Strasbourg, France.
Patients diagnosed with multiple endocrine neoplasia type-1 (MEN1) often initially present with primary hyperparathyroidism (pHPT), and typically undergo surgical intervention. While laboratory tests are fundamental for diagnosis, imaging is crucial for localizing pathological parathyroids to aid in precise surgical planning. In this pictorial review, we will begin by comprehensively examining key imaging techniques and their established protocols, evaluating their effectiveness in detecting abnormal parathyroid glands.
View Article and Find Full Text PDFEnviron Pollut
January 2025
College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China.
Sludge landfilling is widely used in China, accounting for approximately 65% of total sludge disposal, due to its simplicity and cost-effectiveness. However, with increasing land scarcity and stricter environmental regulations, the Chinese government has emphasized reducing sludge landfilling. Despite these efforts, sludge historically disposed of in landfills continues to pose risks, including heavy metal leaching and contamination of groundwater and soil.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2025
College of Science, China University of Petroleum, Beijing 102249 China; Beijing Key Lab of Oil & Gas Optical Detection Technology, China University of Petroleum, Beijing 102249 China; State Key Lab Heavy Oil Processing, China University of Petroleum, Beijing 102249 China. Electronic address:
Non-contact temperature sensors have gained immense popularity due to their inherent benefits, including the absence of physical interaction with targets and rapid response characteristics. In this work, KBaY(MoO):Pr was successfully synthesized utilizing a high-temperature solid-phase method. Experimental studies have indicated that multi-phonon relaxation (MPR), cross-relaxation (CR), and the unique intervalence charge transfer state (IVCT) exhibited by Pr-Mo contribute to the changes in luminescence properties.
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