This paper presents an approach to an optimal operation of a potable water distribution network. The main control objective defined during the preliminary steps was to maximise the use of low-cost power, maintaining at the same time minimum emergency levels in all reservoirs. The combination of dynamic elements (e.g. reservoirs) and discrete elements (pumps, valves, routing) makes this a challenging predictive control and constrained optimisation problem, which is being solved by MINLP (Mixed Integer Non-linear Programming). Initial experimental results show the performance of this algorithm and its ability to control the water distribution process.
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Integr Environ Assess Manag
January 2025
Federal University of the Agreste of Pernambuco, Garanhuns, Brazil.
The proliferation of cyanobacteria has become a significant water management challenge due to the increasing eutrophication of water supply reservoirs. Cyanobacterial blooms thrive on elevated nutrient concentrations and form extensive green mats, disrupting the local ecosystem. Furthermore, many cyanobacterial species can produce toxins that are lethal to vertebrates called cyanotoxins.
View Article and Find Full Text PDFJ Chem Theory Comput
January 2025
Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan.
Solvent environment may significantly affect the equilibria involving flexible solute species, such as proteins and polymers. In the present work, a computation scheme is formulated for the change in the excess chemical potential of a flexible solute molecule upon variation of the solvent condition. The formulation adopts the scheme of error minimization in parallel to the method of Bennett acceptance ratio, and an exact expression is presented that provides the change in the excess chemical potential from solvation free energies computed in two solvent conditions of interest.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
Department of Environmental Sciences, University of Virginia, Charlottesville, Virginia 22904, United States.
Industrialized swine facilities adversely affect the health and well-being of Eastern North Carolina residents in the U.S. and are an issue of environmental racism.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
Stockbridge School of Agriculture, University of Massachusetts, Amherst, Massachusetts 01003, United States.
Concern over nanoplastic contamination of wetland ecosystems has been increasing. However, little is known about the effect of photoaging on the distribution and biological response of the nanoplastics. Here, palladium-labeled polystyrene nanoplastics (PS-Pd NPs) at 0.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Univ. Grenoble Alpes, Univ. Savoie Mont Blanc, CNRS, Grenoble INP, LEPMI 38000 Grenoble, France.
An original approach to characterize electrochemical interfaces at the atomic level, a challenging topic toward the understanding of electrochemical reactivity, is reported. We employed surface resonant X-ray diffraction experiments combined with their simulation using first-principle density functional theory calculations and were thus able to determine the molecular and electronic structures of the partially ionic layer facing the electrode surface, as well as the charge distribution in the surface metal layers. Pt(111) in an acidic medium at an applied potential excluding specific adsorption was studied.
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