Statement Of Problem: Flaws developed during polymerization of restorative materials cause a decrease in mechanical properties.
Purpose: The aim of this study was to determine the effect of polymerization under pressure on the indirect tensile mechanical properties (stiffness and diametral tensile strength) of several light-polymerized composites.
Material And Methods: Five light-polymerized composites were tested: Brilliant, Z100, TPH Spectrum, Prodigy, and Pertac Hybrid. A total of 80 cylindrical disk specimens (6 mm x 2 mm) were prepared for each material in a special mold that enabled polymerization under pressure (PUP). An equal number of specimens were polymerized under surface pressures of 0,.35,.71 and 1.06 MPa (n = 20). Stiffness (N/mm) and diametral tensile strength (DTS) (MPa) were analyzed while loading the specimen to failure with a loading machine. Two-way analysis of variance and Weibull analyses were applied (alpha=5%).
Results: Material type had a statistically significant influence on both DTS and stiffness (P<.0001). Differences up to 33% in DTS and up to 70% in stiffness values were found among the tested materials. Loading (PUP) had a significant influence on stiffness (P<.03) and DTS (P<.0001). PUP caused an increase in DTS values for Brilliant, Z100, and Prodigy of about 20% (P<.001) and increased stiffness only for Brilliant (15%). However, the amount of pressure needed for the improvement was different between materials (interaction between materials and loadings) (P<.0005). Weibull statistics showed that PUP improved the chances for reducing flaws in a material.
Conclusion: Polymerizing material under pressure can improve its DTS and stiffness. However, the pressure needed for the procedure is material dependent.
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http://dx.doi.org/10.1067/mpr.2002.128100 | DOI Listing |
Acc Mater Res
January 2025
School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, Atlanta, Georgia 30322, United States.
Increasing demand for high-purity fine chemicals and a drive for process intensification of large-scale separations have driven significant work on the development of highly engineered porous materials with promise for sorption-based separations. While sorptive separations in porous materials offer energy-efficient alternatives to longstanding thermal-based methods, the particulate nature of many of these sorbents has sometimes limited their large-scale deployment in high-throughput applications such as gas separations, for which the necessary high feed flow rates and gas velocities accrue prohibitive operational costs. These processability limitations have been historically addressed through powder shaping methods aimed at the fabrication of structured sorbent contactors based on pellets, beads or monoliths, commonly obtained as extrudates.
View Article and Find Full Text PDFExpert Opin Drug Deliv
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School of Pharmacy, Shenyang Pharmaceutical University, Shenyang, Liaoning, China.
Introduction: Transdermal patches offer a unique advantage by providing extended therapeutic benefits while maintaining stable plasma drug concentration. The efficacy and safety of patches depend significantly on their ability to adhere to the skin, a feature influenced by various external and internal factors.
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Sci Rep
January 2025
Department of Polymers and Biopolymers, Faculty of Chemistry, Rzeszów University of Technology, 6 Powstańców Warszawy Ave., Rzeszów, 35-959, Poland.
This study presents an investigation of the chemical composition of Aloe vera leaf tissue with a focus on the spatial distribution of compounds. The composition was studied using two mass spectrometry imaging techniques: silver-109 nanoparticles assisted laser desorption/ionization mass spectrometry imaging (AgNPs-LDI-MSI) and laser ablation-remote atmospheric pressure photoionization/chemical ionization mass spectrometry imaging (LARAPPI/CI-MSI) and the identification was aided by ultra-high-performance liquid chromatography and ultra-high-resolution mass spectrometry (UHPLC-UHRMS) analysis. The results showed an abundance of phenolic compounds with antioxidant, antimicrobial, and anti-inflammatory properties, making it a beneficial food additive and food packaging material.
View Article and Find Full Text PDFJ Chromatogr Sci
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Department of Chemistry & Biochemistry, Ohio University, Athens, OH, USA.
The valid method was developed for analyzing empagliflozin in serum/plasma/urine using a molecularly imprinted ghost polymer-solid-phase extraction approach (MISPE) with liquid chromatographic methodology. Methacrylic acid (MAA) was used as the monomer, 2,2 azobis isobutyronitrile as the initiator and ethylene glycol dimethacrylate as the cross-linker in the free radical polymerization procedure. Empagliflozin was loaded onto the polymer and eluted with 1 mL of a 9:1 MeOH:acetic acid solution.
View Article and Find Full Text PDFJ Hazard Mater
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State Key Laboratory of Advanced Environmental Technology, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, 510640, China; Guangdong-Hong Kong-Macao Joint Laboratory for Environmental Pollution and Control and Guangdong Provincial Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou 510640, China.
The effects of micro- and nano-plastics (MNPs) on human health are of global concern because MNPs are ubiquitous, persistent, and potentially toxic, particularly when bound to atmospheric fine particles (PM). Traditional quantitative analysis of MNPs by pyrolysis-gas chromatography-mass spectrometry (Py-GC/MS) is often inaccurate because of false positive signals caused by similar polymers and organic compounds. In this study, a reliable analytical strategy combining HNO digestion and chromatographic peak reconstruction was developed to improve the precision of pyrolysis-gas chromatography-mass spectrometry analysis of multiple MNPs bound to PM.
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