Gravity-induced anomalies in interphase spacing reported for binary eutectics.

Ann N Y Acad Sci

Department of Materials and Metallurgical Engineering, Queen's University at Kingston, Ontario, Canada.

Published: October 2002

It has been reasoned that desirable microstructural refinement in binary eutectics could result from freezing in reduced-gravity. It is recognized that the interphase spacing in a binary eutectic is controlled by solute transport and that, on Earth, buoyancy-driven convection may enhance this. Hence, it has been presumed that the interphase spacing ought to decrease when a eutectic alloy is frozen under conditions of much-reduced gravity, where such buoyancy effects would be largely absent. The result of such speculation has been that many workers have frozen various eutectics under reduced gravity and have reported that, although some eutectics became finer, others showed no change, and some even became coarser. This reported varied behavior will be reviewed in the light of long term studies by the author at Queen's University, including recent microgravity studies in which samples of two eutectic alloy systems, MnBi-Bi and MnSb-Sb, were frozen under very stable conditions and showed no change in interphase spacing.

Download full-text PDF

Source
http://dx.doi.org/10.1111/j.1749-6632.2002.tb05907.xDOI Listing

Publication Analysis

Top Keywords

interphase spacing
16
binary eutectics
8
eutectic alloy
8
gravity-induced anomalies
4
interphase
4
anomalies interphase
4
spacing
4
spacing reported
4
reported binary
4
eutectics
4

Similar Publications

Challenges and Modification Strategies on High-Voltage Layered Oxide Cathode for Sodium-Ion Batteries.

ChemSusChem

September 2024

State Key Laboratory of Advanced Chemical Power Sources, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin, 300071, China.

Sodium-ion batteries (SIBs) have attracted great attention due to their advantages on resource abundance, cost and safety. Layered oxide cathodes (LOCs) of SIBs possess high theoretical capacity, facile synthesis and low cost, and are promising candidates for large scale energy storage application. Increasing operating voltage is an effective strategy to achieve higher specific capacity and also high energy density of SIBs.

View Article and Find Full Text PDF

Regulation of Interface Ion Transport by Electron Ionic Conductor Construction toward High-Voltage and High-Rate LiNiCoMnO Cathodes in Lithium Ion Battery.

Adv Sci (Weinh)

August 2024

Institute for Superconducting and Electronic Materials, Australian Institute for Innovative Materials, University of Wollongong's Innovation Campus, Squires Way, North Wollongong, NSW, 2522, Australia.

Article Synopsis
  • Achieving both high-energy-density and high-power-density in power batteries is challenging, but this study uses atomic layer deposition (ALD) and thermal treatments to create an innovative protective coating on commercial LiNiCoMnO (NCM523) cathodes.
  • The new coating, which features dual conduction, prevents unwanted reactions and promotes lithium transport, enhancing stability and performance at high voltages.
  • The modified battery, Al@EIC-NCM523, shows impressive results with a capacity of 114.7 mAh/g at high rates and retains 74.72% of its capacity after 800 charge cycles, indicating potential for future lithium-ion battery advancements.
View Article and Find Full Text PDF
Article Synopsis
  • Nitrogen-doped carbon submicrospheres (NCSMs) are created through a simple one-pot polymerization reaction at room temperature using dopamine hydrochloride, which provides both carbon and nitrogen.
  • The resulting NCSMs demonstrate impressive performance metrics, including an initial Coulombic efficiency of 84.8%, a sodium storage capacity of 384 mAh/g, and excellent cycling stability with 83.0% capacity retention after 2000 cycles.
  • This environmentally friendly synthesis method not only enhances sodium storage and transport dynamics but also presents a scalable approach for future sodium-ion battery commercialization.
View Article and Find Full Text PDF

Ultrastructure and fractal property of chromosomes in close-to-native yeast nuclei visualized using X-ray laser diffraction.

Sci Rep

July 2023

Department of Physics, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-Ku, Yokohama, Kanagawa, 223-8522, Japan.

Genome compaction and activity in the nucleus depend on spatiotemporal changes in the organization of chromatins in chromosomes. However, the direct imaging of the chromosome structures in the nuclei has been difficult and challenging. Herein, we directly visualized the structure of chromosomes in frozen-hydrated nuclei of budding yeast in the interphase using X-ray laser diffraction.

View Article and Find Full Text PDF

Hard carbon, as the most promising commercial anode materials of sodium-ion batteries (SIBs), has suffered from the coupling limitations on initial Coulombic efficiency (ICE), capacity, and rate capability. Herein, to break such coupling limitations, sulfur-rich nitrogen-doped carbon nanomaterials (S-NC) were synthesized by a synergistic modification strategy, including structure/morphology regulation and dual heteroatom doping. The small specific surface area of S-NC is beneficial for inhibiting excessive growth of solid electrolyte interphase (SEI) film and irreversible interfacial reaction.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!