Light-controlled gas permeability of mesoporous silica glass bearing photochromic spironaphthoxazine on its surface.

Chem Commun (Camb)

Department of Applied Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Sakai, Osaka 599-8531, Japan.

Published: October 2002

N2 and CO2 gas permeability of mesoporous silica glass bearing photochromic indolinospironaphth[2,1-b][1,4]oxazine through a covalent linkage was controlled by photo-irradiation: the photo-isomerization of the spironaphthoxazine to the photomerocyanine form suppressed the gas permeation of the glass.

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http://dx.doi.org/10.1039/b208267eDOI Listing

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