MX was widely considered as one of the most important disinfection by-products (DPBs) and as the strong carcinogen in the chlorinated drinking water. Some model compounds which have been classified into four families were chlorinated at laboratory conditions. MX was produced only in the chlorinated substituted aromatic aldehydes and amino acids, while a possible new compound (COHC) was found in some substituted aromatic aldehydes, chlorinated substituted aromatic acids and phenols. Through the analysis of the peaks presented in mass spectrum, the composition and structure of the new compound are proposed as 2-chloro-5-oxo-3-hexene diacyl chloride (COHC) which could cause interference in the detection of MX. COHC has also been found in drinking water and extracted chlorinated fulvic acid solution from the sediment and water of Tai Lake, so it should bring about more attention.
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http://dx.doi.org/10.1016/s0043-1354(02)00190-2 | DOI Listing |
J Phys Chem A
December 2024
Astrophysics Branch, NASA Ames Research Center, MS 245-6, Moffett Field, California 94035, United States.
Anharmonic computations reveal an intense, narrow (20 cm, 0.043 μm) absorption feature at approximately 2160 cm (4.63 μm) in the vibrational spectra of 14 prototypical singly isocyano-substituted polycyclic aromatic hydrocarbons (NC-PAHs) attributed to the NC stretching mode.
View Article and Find Full Text PDFInorg Chem
December 2024
School of Chemical Science and Engineering, Tongji University, Shanghai 200092, P. R. China.
The vapor-phase alkylation of phenol with methanol was investigated on X zeolites and modified X zeolites. First, the difference of product distribution was tested between acid zeolite (HZSM-5, HX, HMCM-22, and Hβ) and basic zeolite X (KX and CsX). Then, X zeolites were modified with Li, K, Cs, Ca, Mg, La, and Ce ion exchange to adjust the acid-base properties of the zeolites.
View Article and Find Full Text PDFACS Omega
December 2024
School of Pharmacy, Guizhou Provincial Engineering Technology Research Center for Chemical Drug R&D, Guizhou Medical University, Guiyang 550014, P. R. China.
A transition metal-free domino Michael/S2/aromatization annulation of 2-pyridylacetates with bromonitroolefins has been developed. A wide range of substrates containing various substituted groups was compatible with the present methodology and afforded functionalized indolizines with moderate to excellent yield (up to 99% yield). In addition, the potential practicality of the method stood out through scale-up reactions and further transformations to other valuable compounds.
View Article and Find Full Text PDFChem Commun (Camb)
December 2024
Department of Chemistry, School of Pharmacy, Air Force Medical University, Xi'an, 710032, China.
An efficient synthesis of continuously substituted quinoline derivatives palladium-catalyzed intramolecular 6- imidoylative cyclization of -alkenyl aryl isocyanides with (hetero)aryl halides or vinylic triflates has been developed. The reaction proceeds through the concerted metalation-deprotonation (CMD) mechanism by activation of a vinyl C-H bond with imidoylpalladium assisted by the carboxylate.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2024
Zhejiang Sci-Tech University, Hangzhou 310018, China. Electronic address:
Excited-state intramolecular proton transfer (ESIPT) reactions are one of the fundamental energy transformation reactions in catalysis and biological process. The combining ESIPT with the twisted intramolecular charge transfer (TICT) brings the richness of optical, photoelectronic performances to certain functional compounds. Delineating the mechanism of ESIPT + TICT reactions and further understanding why a specific functional group dominates are fundamentally crucial for the design and application of the functionally photoelectric materials.
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