FT-IR spectroscopy was applied to investigate 15 different carotenoids. The following compounds were examined: beta-carotenone (1); semi-beta-carotenon-epoxide (2); beta-apo-8'-carotenal (3); ethyl-beta-apo-8'-carotenoate (4); beta-citraurin (5); 5,6-Epoxy-beta-caroten-8'-al (6); beta-citraurin-epoxide (7); apo-10'-violaxanthal (8); persicaxanthin (9); capsylaldehyde (10); capsanthylal (11); retinol (12); retinal (13); retinoic acid (14); and bixin (15). Some characteristic functional groups (Cz.dbnd;C, Cz.dbnd;O, CHO, OH, etc.) were identified. We focused on the influence of conjugation of the keto-, aldehyde- and ester groups on the absorption of the Cz.dbnd;C bonds. This method is useful in the fast analysis of the biologically important carotenoids especially if there are small samples available.
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http://dx.doi.org/10.1016/s0165-022x(02)00113-6 | DOI Listing |
Sci Rep
December 2024
Department of Chemical Engineering, RVR & JC College of Engineering (A), Guntur, Andhra Pradesh, 522019, India.
The study analyzed the aqueous leaf extracts of Moringa oleifera and Musa sps. for phytochemical components, including flavonoids, sterols, saponins, tannins, and glycosides. The LC-MS analysis revealed gingerol, vicenin-2, caffeic acid, quercetin, and other compounds in the extracts.
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December 2024
Department of Organic and Polymer Chemistry, Faculty of Chemistry, Kharazmi University, Tehran, 15719-14911, Iran.
This study investigates the repurposing of asphaltene, a petroleum waste product, as a catalyst for organic reactions. Sulfonated asphaltene was synthesized and evaluated for its efficacy in catalyzing the Mannich reaction, displaying notable diastereoselectivity and operating effectively under mild conditions. Characterization of the catalyst's chemical composition, structure, and thermal stability was conducted using FT-IR, TGA, XRD, CHN, BET-BJH, SEM, and EDS analyses.
View Article and Find Full Text PDFGels
November 2024
State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources, College of Chemistry, Xinjiang University, Urumqi 830017, China.
In this study, a novel polyacrylate-co-vinyl imidazole hydrogel-supported palladium (Pd) catalyst (P(AA-co-VI)@Pd) was prepared through heat-initiated polymerization, starting with the formation of a complex between vinyl imidazole and palladium chloride, followed by the addition of 75% neutralized acrylic acid (AA), crosslinking agent, and initiator. The structure and morphology of the catalyst were characterized using ICP-OES, SEM, EDX, Mapping, FT-IR, TGA, XRD, XPS and TEM techniques. It was confirmed that the catalyst exhibited excellent compatibility with water solvent and uniform distribution of Pd.
View Article and Find Full Text PDFAppl Spectrosc
December 2024
The Graduate School, University of Santo Tomas, Manila, Philippines.
Acute leukemia, a highly perilous cancer, is diagnosed using invasive procedures like bone marrow aspirate and biopsy (BMA/BMB). This study investigated the use of artificial intelligence (AI)-enhanced Fourier transform infrared (FT-IR) spectroscopy as a non-invasive, reagent-free diagnostic alternative with high sensitivity and specificity. The spectral peak patterns of peripheral blood smears (PBS) from clinically healthy individuals ( = 50) BMA/BMB-confirmed acute leukemia patients ( = 50) were examined in the 1800-850 cm range.
View Article and Find Full Text PDFPDA J Pharm Sci Technol
December 2024
Laboratory of Quality Control, Department of Quality Control; Bio-Manguinhos/Fiocruz
The typing of micro-organisms in pharmaceutical factories often relies on expensive and time-consuming molecular techniques. So, the implementation of cheap, fast and reliable typing methods in the routine would speed up the investigation procedures improving the contamination control strategy. The Fourier-transform infrared (FT-IR) spectroscopy is a method that generates spectra, that enables to micro-organisms typing within 3 h.
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