AI Article Synopsis
- Dialkoxydichlorosilanes react with silanol groups in layered silicates to form new crystalline silicate structures with five-membered rings.
- The reaction occurs almost completely, leading to significant structural changes in the silicate layers.
- This process offers a new method for designing and constructing unique silicate frameworks using a gentle chemical approach.
Article Abstract
Dialkoxydichlorosilanes ((RO)2SiCl2, R = alkyl) react almost completely with interlayer silanol groups in a layered silicate octosilicate to create a new crystalline silicate structure consisting of new five-membered rings arranged regularly on both sides of the silicate layers. The introduction of dialkoxysilyl groups to the interlamellar region of layered silicates with regular reaction sites provides a new methodology for the design and construction of novel crystalline silicate frameworks by a soft chemical route.
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| http://dx.doi.org/10.1021/ja027512t | DOI Listing |
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