AI Article Synopsis
- The study describes a hydrothermal reaction that combines V2O5, Cu(CH3COO)2·H2O, 1,2-diaminopropane, and [N(CH3)4]OH to create a unique three-dimensional solid.
- The resulting compound is identified as [(Cu(1,2-pn)2)7-(V16O38(H2O))2]·4H2O, featuring mixed-valence [V16O38(H2O)]7- clusters.
- These clusters are linked together using mu 2-[Cu(1,2-pn)2]2+ groups, showcasing an innovative structural framework.
Article Abstract
The hydrothermal reaction of V2O5, Cu(CH3COO)2.H2O, 1,2-diaminopropane and [N(CH3)4]OH yields the novel three-dimensional open-framework solid [(Cu(1,2-pn)2)7-(V16O38(H2O))2].4H2O constructed from the new mixed-valence [V16O38(H2O)]7- clusters interconnected through mu 2-[Cu(1,2-pn)2]2+ groups.
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| http://dx.doi.org/10.1039/b206880j | DOI Listing |
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