We report emissive devices exhibiting electroluminescence in the solution phase. The principle operating mechanism for these devices--direct electronic carrier injection from the electrodes into the carrier bands of the dissolved polymer--resembles that of a conventional solid-state organic light-emitting diode and is distinct from the solvent-mediated electrochemical devices recently reported by Chang et al.
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http://dx.doi.org/10.1039/b205298a | DOI Listing |
Adv Mater
February 2023
Department of Chemistry, Research Institute for Convergence of Basic Science, and Research Institute for Natural Sciences, Hanyang University, Seoul, 04763, South Korea.
Semiconducting lead halide perovskite nanocrystals (PNCs) are regarded as promising candidates for next-generation optoelectronic devices due to their solution processability and outstanding optoelectronic properties. While the field of light-emitting diodes (LEDs) and photovoltaics (PVs), two prime examples of optoelectronic devices, has recently seen a multitude of efforts toward high-performance PNC-based devices, realizing both devices with high efficiencies and stabilities through a single PNC processing strategy has remained a challenge. In this work, diphenylpropylammonium (DPAI) surface ligands, found through a judicious ab-initio-based ligand search, are shown to provide a solution to this problem.
View Article and Find Full Text PDFACS Appl Mater Interfaces
July 2018
State Key Laboratory of Silicon Materials and School of Material Science and Engineering , Zhejiang University, Hangzhou 310027 , China.
Solution-processed organometallic halide perovskites have obtained rapid development for light-emitting diodes (LEDs) and solar cells (SCs). These devices are fabricated with similar materials and architectures, leading to the emergence of perovskite-based light-emitting solar cells (LESCs). The high quality perovskite layer with reduced nonradiative recombination is crucial for achieving a high performance device, even though the carrier behaviors are fundamentally different in both functions.
View Article and Find Full Text PDFJ Phys Chem A
December 2017
Department of Chemistry, New Mexico Institute of Mining & Technology, Socorro, New Mexico 87801, United States.
This report investigates the excited-state properties of a series of N-aryl-2,3-naphthalimides along with their fabrication into OLEDs and electroluminescence measurements. The N-aryl-2,3-NIs substituted specifically with chloro, fluoro, and methoxy substituents were chosen because of their unique propensity to display two emission bands or panchromatic fluorescence. Using the Lippert-Mataga analysis along with TD-DFT calculations, the excited states were determined to be n,π* and π,π*.
View Article and Find Full Text PDFACS Nano
November 2014
The Edward S. Rogers Department of Electrical and Computer Engineering, University of Toronto , 10 King's College Road, Toronto, Ontario M5S 3G4, Canada.
Colloidal quantum dot films have seen rapid progress as active materials in photodetection, light emission, and photovoltaics. Their processing from the solution phase makes them an attractive option for these applications due to the expected cost reductions associated with liquid-phase material deposition. Colloidally stable nanoparticles capped using long, insulating aliphatic ligands are used to form semiconducting, insoluble films via a solid-state ligand exchange in which the original ligands are replaced with short bifunctional ligands.
View Article and Find Full Text PDFChem Commun (Camb)
September 2002
Department of Chemistry, Imperial College of Science Technology and Medicine, Exhibition Road, South Kensington, London, UK SW7 2AY.
We report emissive devices exhibiting electroluminescence in the solution phase. The principle operating mechanism for these devices--direct electronic carrier injection from the electrodes into the carrier bands of the dissolved polymer--resembles that of a conventional solid-state organic light-emitting diode and is distinct from the solvent-mediated electrochemical devices recently reported by Chang et al.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!