The selenium(IV) diimide AdN=Se=NAd (Ad = 1-adamantyl) adopts a monomeric structure with a Z,E configuration in the solid state whereas the seleninylamine OSe(mu-NBut)2SeO crystallizes as the cis-dimer.
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Experimental and theoretical investigations of structural trends for selenium(IV) imides and oxides: X-ray structure of Se3(NAd)2.
Inorg Chem
March 2004
Departments of Chemistry, University of Calgary, 2500 University Drive N.W., Calgary, Alberta, Canada T2N 1N4.
The thermal decomposition of Se(NAd)(2) (Ad = 1-adamantyl) in THF was monitored by (77)Se NMR and shown to give the novel cyclic selenium imide Se(3)(NAd)(2) as one of the products. An X-ray structural determination showed that Se(3)(NAd)(2) is a puckered five-membered ring with d(Se-Se) = 2.404(1) A and |d(Se-N)| = 1.
View Article and Find Full Text PDFA monomeric selenium(IV) diimide and a dimeric seleninylamine.
Chem Commun (Camb)
September 2002
Department of Chemistry, University of Oulu, P.O. Box 3000, FIN-90401, Oulu, Finland.
The selenium(IV) diimide AdN=Se=NAd (Ad = 1-adamantyl) adopts a monomeric structure with a Z,E configuration in the solid state whereas the seleninylamine OSe(mu-NBut)2SeO crystallizes as the cis-dimer.
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