A computer simulation of thermofluctuation nucleation of kinks on dislocations and their dynamics is carried out in the framework of the two-dimensional Frenkel-Kontorova model. It is shown that at relatively low temperatures and applied stresses the kinks can appear as a result of developing instability of phonon modes localized in the vicinity of the dislocation. The transition from this mechanism to the ordinary thermofluctuation kink nucleation with temperature increase can reveal itself in the peculiarities of yield stress temperature dependence.
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http://dx.doi.org/10.1103/PhysRevE.66.027201 | DOI Listing |
J Am Chem Soc
January 2025
Department of Chemical and Biomolecular Engineering, University of Houston, Houston, Texas 77204, United States.
Here we demonstrate how a biologically relevant molecule, riboflavin (vitamin B2), operates by a dual mode of action to effectively control crystallization of ammonium urate (NHHU), which is associated with cetacean kidney stones. In situ microfluidics and atomic force microscopy experiments confirm a strong interaction between riboflavin and NHHU crystal surfaces that substantially inhibits layer nucleation and spreading by kinetic mechanisms of step pinning and kink blocking. Riboflavin does not alter the distribution of tautomeric urate isomers, but its adsorption on NHHU crystal surfaces does interfere with the effects of minor urate tautomer by limiting its ability to induce NHHU crystal defects while also suppressing NHHU nucleation and inhibiting crystal growth by 80% at an uncharacteristically low modifier concentration.
View Article and Find Full Text PDFNano Lett
May 2024
CAS Key Laboratory of Standardization and Measurement for Nanotechnology, National Center for Nanoscience and Technology, Beijing 100190, China.
Science
April 2024
Department of Materials Science and Engineering, University of California, Berkeley, CA, USA.
Single-phase body-centered cubic (bcc) refractory medium- or high-entropy alloys can retain compressive strength at elevated temperatures but suffer from extremely low tensile ductility and fracture toughness. We examined the strength and fracture toughness of a bcc refractory alloy, NbTaTiHf, from 77 to 1473 kelvin. This alloy's behavior differed from that of comparable systems by having fracture toughness over 253 MPa·m, which we attribute to a dynamic competition between screw and edge dislocations in controlling the plasticity at a crack tip.
View Article and Find Full Text PDFMaterials (Basel)
February 2024
Department of Mechanical Engineering, The Pennsylvania State University, University Park, PA 16802, USA.
Graphite IG-110 is a synthetic polycrystalline material used as a neutron moderator in reactors. Graphite is inherently brittle and is known to exhibit a further increase in brittleness due to radiation damage at room temperature. To understand the irradiation effects on pre-existing defects and their overall influence on external load, micropillar compression tests were performed using in situ nanoindentation in the Transmission Electron Microscopy (TEM) for both pristine and ion-irradiated samples.
View Article and Find Full Text PDFNanoscale
July 2023
CAS Key Laboratory of Standardization and Measurement for Nanotechnology, National Center for Nanoscience and Technology, Beijing 100190, P.R. China.
One key issue to promote the industrialization of two-dimensional (2D) materials is to grow high-quality and large-scale 2D materials. Investigations of the growth mechanism and growth dynamics are of fundamental importance for the growth of 2D material, in which imaging is highly needed. By applying different imaging techniques, details for growth process, including nucleation and morphology evolution, can be obtained.
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