Differentiation of mobile and immobile pesticides on anionic clays by 1H HR MAS NMR spectroscopy.

Chem Commun (Camb)

Laboratoire de Synthèse et Etude des Systèmes à Intérêt Biologique, Université Blaise Pascal, CNRS UMR 6504, France.

Published: November 2001

Adsorbed vs. intercalated MCPA (4-chloro-2-methylphenoxyacetic acid) in highly hydrated clays taken as a soil model were clearly distinguished by 1H HR MAS NMR; adsorbed herbicide gave sharp signals indicating high mobility while intercalated herbicide gave very wide unresolved spectra due to its strong interaction with the solid matrix.

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Source
http://dx.doi.org/10.1039/b106964kDOI Listing

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