Structures of bromoalkanes' photodissociation in solution by means of ultrafast extended x-ray absorption fine-structure spectroscopy.

D A Oulianov I V Tomov A S Dvornikov P M Rentzepis

Proc Natl Acad Sci U S A

Department of Chemistry, University of California, Irvine, CA 92697, USA.

Published: October 2002

The structures of initial and final products of bromoalkanes' photodisociation reaction in cyclohexane solution have been measured with a bond length accuracy of 0.02 A by means of ultrafast time-resolved extended x-ray absorption fine structure spectroscopy. The photoredaction mechanism is also discussed.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC130498	PMC
http://dx.doi.org/10.1073/pnas.192447199	DOI Listing

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