We introduce quantum dimer models on lattices made of corner-sharing triangles. These lattices include the kagome lattice and can be defined in arbitrary geometry. They realize fully disordered and gapped dimer-liquid phase with topological degeneracy and deconfined fractional excitations, as well as solid phases. Using geometrical properties of the lattice, several results are obtained exactly, including the full spectrum of a dimer liquid. These models offer a very natural-and maybe the simplest possible-framework to illustrate general concepts such as fractionalization, topological order, and relation to Z2 gauge theories.
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http://dx.doi.org/10.1103/PhysRevLett.89.137202 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
East China Normal University, State Key Laboratory of Precision Spectroscopy, 500 Dongchuan Rd., 200241, Shanghai, CHINA.
Near-infrared (NIR) triplet dyes are the cornerstones of cutting-edge biomedical and material applications. The difficulty in rational development of triplet dyes increases exponentially as the absorption wavelength shifts deeper into the NIR range. Although classical H-/J-typed packing of NIR dyes has the potential to enhance intersystem crossing (ISC) compared with that in single-chromophore dyes, the triplet state quantum yields remain limited in such strategy.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Physics, University of Basel, Klingelbergstrasse 82, 4056 Basel, Switzerland.
High-precision molecular manipulation techniques are used to control the distance between radical molecules on superconductors. Our results show that the molecules can host single electrons with a spin 1/2. By changing the distance between tip and sample, a quantum phase transition from the singlet to doublet ground state can be induced.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Institut für Anorganische Chemie, Freie Universität Berlin, Fabeckstraße 34-36, D-14195 Berlin, Germany.
Herein, we report the solvent-dependent reactivity of Fe(CO) toward AsF in either anhydrous HF or liquid SO. The reaction of Fe(CO) with the superacid HF/AsF leads to the protonation of the iron center and allows for the first-time structural characterization of [FeH(CO)] in the solid state, representing one of the most acidic transition metal hydride complexes to ever be isolated and structurally characterized. In the aprotic but oxidation-stable solvent SO, Fe(CO) is oxidized and dimerized to [Fe(CO)], which is isoelectronic with well-known Mn(CO).
View Article and Find Full Text PDFNano Lett
January 2025
Institut für Experimentelle und Angewandte Physik, Christian-Albrechts-Universität, 24098 Kiel, Germany.
The mechanical coupling between molecules represents a promising route for the development of molecular machines. Constructing molecular gears requires easily rotatable and mutually interlocked pinions. Using scanning tunneling microscopy (STM), it is demonstrated that aluminum phthalocyanine (AlPc) molecules on Pb(100) exhibit these properties.
View Article and Find Full Text PDFMicrosc Microanal
January 2025
Stuttgart Center for Electron Microscopy, Max Planck Institute for Solid State Research, Heisenbergstraße 1, Stuttgart 70569, Germany.
In the field of quantum materials, understanding anomalous behavior under charge degrees of freedom through bond formation is of fundamental importance, with two key concepts: Dimerization and charge order at different cation sites. The coexistence of both dimerization and charge ordering is unusually found in NaRu2O4, even in its metallic state at room temperature. Our work unveils the origin of the interplay of these effects within metallic single-crystalline NaRu2O4.
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