Copper(II) nitrate reacts with the rigid polydentate triple-connecting dpyatriz ligand in acetonitrile to an unprecedented infinite molecular ladder in which five-coordinated copper pseudo-dimer are bridged by nitrate anions and the coordination polymer chains are linked by hexacoordinated copper ions leading to the formation of large guest cavities.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/b203394a | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Sterically Induced Enhancement in the Electrochemical Stability of Salen-Type Cathode Materials.
Polymers (Basel)
January 2025
Department of Chemistry, St. Petersburg University, Universitetskaya nab., 7/9, Saint Petersburg 199034, Russia.
This study investigates the electrochemical degradation mechanisms of nickel-salen (NiSalen) polymers, with a focus on improving the material's stability in supercapacitor applications. We analyzed the effects of steric hindrance near the nickel center by incorporating different bulky substituents into NiSalen complexes, aiming to mitigate water-induced degradation. Electrochemical performance was assessed using cyclic voltammetry, operando conductance, and impedance measurements, while X-ray photoelectron spectroscopy (XPS) provided insights into molecular degradation pathways.
View Article and Find Full Text PDFMetal-Coordinated Polymer-Inorganic Hybrids: Synthesis, Properties, and Application.
Polymers (Basel)
January 2025
Department of Materials Science and Engineering, Iowa State University, Ames, IA 50011, USA.
This review examines the recent advancements and unique properties of polymer-inorganic hybrid materials formed through coordination bonding (Class II hybrids), which enable enhanced functionality and stability across various applications. Here, we categorize these materials based on properties gained through complexation, focusing on electrical conductivity, thermal stability, photophysical characteristics, catalytic activity, and nanoscale self-assembly. Two major synthetic approaches to making these hybrids include homogeneous and heterogeneous methods, each with distinct tradeoffs: Homogeneous synthesis is straightforward but requires favorable mixing between inorganic and polymer species, which are predominantly water-soluble complexes.
View Article and Find Full Text PDFPorosity Tunable Metal-Organic Framework (MOF)-Based Composites for Energy Storage Applications: Recent Progress.
Polymers (Basel)
January 2025
Department of Physics, Faculty of Science, Kasetsart University, Bangkok 10900, Thailand.
To solve the energy crisis and environmental issues, it is essential to create effective and sustainable energy conversion and storage technologies. Traditional materials for energy conversion and storage however have several drawbacks, such as poor energy density and inadequate efficiency. The advantages of MOF-based materials, such as pristine MOFs, also known as porous coordination polymers, MOF composites, and their derivatives, over traditional materials, have been thoroughly investigated.
View Article and Find Full Text PDFLuminescent Lanthanide Infinite Coordination Polymers for Ratiometric Sensing Applications.
Molecules
January 2025
College of Chemistry and Chemical Engineering, Central South University, Changsha 410017, China.
Ratiometric lanthanide coordination polymers (Ln-CPs) are advanced materials that combine the unique optical properties of lanthanide ions (e.g., Eu, Tb, Ce) with the structural flexibility and tunability of coordination polymers.
View Article and Find Full Text PDFColor, Structure, and Thermal Stability of Alginate Films with Raspberry and/or Black Currant Seed Oils.
Molecules
January 2025
Department of Analytical Chemistry and Applied Spectroscopy, Faculty of Chemistry, Nicolaus Copernicus University in Toruń, Gagarina 7, 87-100 Toruń, Poland.
In this study, biodegradable and active films based on sodium alginate incorporated with different concentrations of oils (25% and 50%) from fruit seeds were developed for potential applications in food packaging. The ultraviolet and visible (UV-VIS) spectra of raspberry seed oil (RSO) and black currant seed oil (BCSO) indicated differences in bioactive compounds, such as tocopherols, phenolic compounds, carotenoids, chlorophyll, and oxidative status (amounts of dienes, trienes, and tetraenes) of active components added to alginate films. The study encompassed the color, structure, and thermal stability analysis of sodium alginate films incorporated with RSO and BCSO and their mixtures.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!