Reaction of HCl with [RhCl(C2H4)(PR3)]2 affords the dinuclear alkylrhodium(III) complex [RhCl2(C2H5)(PR3)]2, the structure of which has been determined crystallographically. PR3 is the formerly unknown trialkyl phosphine tBu2PCH2CH2C6H3-2,6-Me2, prepared in three steps from tBuPCl2. Treatment of the title compound with CO gives the mononuclear rhodium dicarbonyl cis-[RhCl(CO)2(PR3)], being the first fully characterized complex of this type.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/ja020560t | DOI Listing |
Publication Analysis
Top Keywords
dinuclear alkylrhodiumiii
8
alkylrhodiumiii complex
8
unprecedented dinuclear
4
complex built
4
built 14-electron
4
14-electron [rhcl2alkylpr3]
4
[rhcl2alkylpr3] units
4
units reaction
4
reaction hcl
4
hcl [rhclc2h4pr3]2
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!