Three-dimensional network structures of [Ru(II/III)(2)(O(2)CMe)(4)](3)[M(III)(CN)(6)] (M = Cr, Fe, Co) composition have been formed and their magnetic properties characterized. [Ru(II/III)(2)(O(2)CMe)(4)](3)[M(III)(CN)(6)] (M = Cr, Fe, Co) have nu(CN) IR absorptions at 2138, 2116, and 2125 cm(-1) and have body-centered unit cells (a = 13.34, 13.30, and 13.10 A, respectively) with -M-Ctbd1;N-Ru=Ru-Ntbd1;C-M- linkages along all three Cartesian axes. [Ru(II/III)(2)(O(2)CMe)(4)](3)[Cr(III)(CN)(6)] magnetically orders as a ferrimagnet (T(c) = 33 K) and has an unusual constricted hysteresis loop.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/ja020552c | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Exploring Solid Magnetic Liposomes for Organic Pollutant Removal from Wastewater: The Role of Lipid Composition.
ACS Appl Mater Interfaces
January 2025
Department of Physical and Chemical Sciences, Università degli Studi dell'Aquila, L'Aquila 67100, Italy.
Solid magnetic liposomes (ML, nanocomposites comprising lipid bilayers that incorporate magnetic nanoparticles) may be used in wastewater remediation: the lipid bilayer creates an environment where organic pollutants preferentially partition instead of water and the manipulation of ML with an external magnet enables an easy recovery from water. This study aimed to assess the system's potential for water remediation, focusing on ML ability to remove common pollutants in industrial wastewater. Specifically, alkylphenol ethoxylates (APEO) were used as the archetype for organic pollutants.
View Article and Find Full Text PDFThe first experimentally obtained dataset on processing parameters and properties of soft magnetic composites.
Sci Data
January 2025
Institute of Physics, Faculty of Science, Pavol Jozef Šafárik University in Košice, Park Angelinum 9, 041 54, Košice, Slovak Republic.
The present work describes the process of the creation and analysis of the first dataset containing processing parameters and functional properties of soft magnetic composites (SMC). All data were obtained experimentally using Fe-3% MgO system. When creating samples, parameters such as a size of MgO nanoparticles, pressing pressure, sintering temperature, time and atmosphere were varied.
View Article and Find Full Text PDFEffect of magnetized water on the fundamental grouting properties of cement grout under varying magnetization conditions.
Sci Rep
January 2025
College of Electrical and Information Engineering, Hunan University of Science and Technology, Xiangtan, 411201, Hunan, People's Republic of China.
The development and modification of grouting materials constitute crucial factors influencing the effectiveness of grouting. Given the pivotal role of water in the hydration of cement-based composite materials and construction processes, this study proposes an exploratory approach using green, economical magnetized water technology to enhance the performance of cement grouts. The research systematically investigates the effects of magnetized water on the fundamental grouting properties (stability, rheological behavior, and stone body strength) of cement grouts, prepared under varying magnetization conditions (including magnetic intensity, water flow speed, and cycle times).
View Article and Find Full Text PDF"Innovative multidisciplinary care in pediatric magnet aspiration: A case report".
Int J Surg Case Rep
January 2025
Department of Pediatric Surgery, The University of Child Health Sciences and The Children's Hospital, Lahore, Lahore - Kasur Rd, Nishtar Town, Lahore, Punjab, Pakistan 54000.
Introduction: Foreign body (FB) inhalation is a potentially life-threatening condition in children. Magnets, being rare, aspirated objects, pose significant threat due to their physical and magnetic properties.
Case Presentation: A 10-year-old girl with a history of magnet aspiration went into respiratory distress due to dislodgement of magnet to opposite main bronchus following failed attempt of removal via Rigid Bronchoscopy.
Peroxydisulfate activation by synergized modified AgCuFeO@GO nanoparticle electrode with anchored MnO in cefixime three-dimensional electrochemical degradation: Optimization and mechanisms.
J Environ Manage
January 2025
Environmental Health Engineering Research Center, Kerman University of Medical Sciences, Kerman, Iran. Electronic address:
Cefixime (CFX) is a potent antibiotic against gram-positive and gram-negative bacteria that resists degradation and typical removal procedures. This research aimed to synthesize a modified AgCuFeO@GO nanoparticle electrode with anchored MnO for removing CFX by three-dimensional electrochemical oxidation. The physical and chemical characteristics of the nanocomposite were evaluated using various techniques, including FESEM, XRD, EDS-mapping, FTIR, BET, VSM, and TGA.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!