The title compound, C(18)H(18)N(4)S(4).2C(3)H(7)NO, crystallizes with the dibenzyl dihydrazinecarbodithioate molecule residing on a crystallographic inversion centre. The molecule adopts a trans conformation with respect to the central C-C single bond. The dihedral angle between the phenyl group and the thiothiosemicarbazone unit is 74.1 (1) degrees.
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http://dx.doi.org/10.1107/s0108270102011411 | DOI Listing |
We report a series of dibenzyl isophthalates (DBIs) as novel hosts for room-temperature phosphorescence (RTP) host-guest systems, achieving RTP quantum yields (QY) of up to 77% or lifetimes of up to 21.0 s with the guest coronene- . Furthermore, a 4,4'-Br substituted DBI was used to form host-guest RTP systems with 15 different aromatic guest molecules, to tune the phosphorescence emission color from blue to red and to demonstrate the versatility of the host.
View Article and Find Full Text PDFChemSusChem
December 2024
Faculty of Medicine and Health, University of New England, Armidale, NSW, 2351.
Levoglucosenone is an important platform chemical and the principal product of acid-catalyzed cellulose pyrolysis, formed through several intermediates including levoglucosan. An acid-catalyzed redox isomerization of substituted 6,8-dioxabicyclo[3.2.
View Article and Find Full Text PDFFood Chem Toxicol
December 2024
Member Expert Panel for Fragrance Safety, The Journal of Dermatological Science (JDS), Department of Dermatology, Hamamatsu University School of Medicine, 1-20-1 Handayama, Higashi-ku, Hamamatsu, 431-3192, Japan.
Environ Sci Pollut Res Int
December 2024
Laboratoire Bio-Géosciences Et Ingénierie Des Matériaux, Ecole Normale Supérieure, Université Hassan II de Casablanca, Casablanca, Morocco.
The impact of N,1-dibenzyl-5-methyl-1H-pyrazol-3-carboxamide (BPC) on the carbon steel (CS) corrosion in hydrochloric acid (1 M) was studied in this work, considering concentration and temperature effects. Electrochemical investigation indicated that BPC functions as a mixed-type inhibitor. For an optimal BPC concentration of 125 ppm, the inhibition efficiency of 91.
View Article and Find Full Text PDFDokl Biochem Biophys
December 2024
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russia.
One of the main modern approaches to the creation of effective drugs is the design of new biologically active substances containing two or more pharmacophore groups in their structure. In recent years, there have been many publications on the synthesis and study of biological activity, including antitumour activity, of new organo-arsenic compounds. It is known that spatially hindered phenols can also have antitumor activity, so the synthesis and study of hybrid compounds based on organo-arsenic compounds and spatially hindered phenols is a relevant area of research.
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