In this work, we analyzed pollution in the river Arno using a non-steady advection-dispersion-reaction equation (ADRE) calibrated on experimental data. We examined the influence different pollution control strategies have on dissolved oxygen (DO). We considered (i) flow rate variation; (ii) local oxygenation at critical points; (iii) dynamic modification of wastewater load. Results indicate first, that reservoir management is effective in reducing pollution; second, that local oxygenation is necessary to ensure that DO does not fall below safety levels; and finally, that tuning wastewater loads appears to be impractical to manage the river quality given the stringent limitations it would impose on the industrial effluents.
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http://dx.doi.org/10.1016/s0043-1354(01)00483-3 | DOI Listing |
Sci Total Environ
December 2024
Department of Earth Sciences, University of Florence, 50121 Florence, Italy.
Fluvial ecosystems are among the main drivers of microparticles (MPC) in the form of both synthetic polymers (i.e. microplastics; MPs) and natural-based textile fibers (MF) to the seas.
View Article and Find Full Text PDFSci Total Environ
December 2024
Department of Civil and Environmental Engineering (DICEA), Univpersità degli Studi di, Firenze, Via di S. Marta 3, Firenze 50139, Italy.
The study addresses the challenge of integrating complex landscape-hydrological interactions into predictive models for improved water resource management. The aim is to investigate the effectiveness of landscape metrics-quantitative indices measuring landscape composition and configuration-as predictors of WES in the Arno River Basin, Italy. Utilizing two hydrological models alongside a random forest algorithm, we assessed spatial and temporal variations in water yield, runoff, and groundwater recharge.
View Article and Find Full Text PDFSci Total Environ
September 2024
University of Florence, Department of Earth Sciences, Firenze, Italy.
The distribution of geochemical species are typically either (log)normally distributed or follow power laws. Here we link these types of distributions to the dynamics of the system that generates these distributions, showing that power laws can emerge in dissipative systems far from equilibrium while (log)normal distributions are found for species for which the concentrations are close to equilibrium. We use observations of the chemical composition of river water from the sampling space in central Italy as well as discharge data to test this interpretation.
View Article and Find Full Text PDFAnal Bioanal Chem
June 2023
Department of Chemistry and Industrial Chemistry, University of Pisa, 56124, Pisa, Italy.
The total mass of individual synthetic polymers present as microplastic (MP < 2 mm) pollutants in the sediments of interconnected aquatic environments was determined adopting the Polymer Identification and Specific Analysis (PISA) procedure. The investigated area includes a coastal lakebed (Massaciuccoli), a coastal seabed (Serchio River estuarine), and a sandy beach (Lecciona), all within a natural park area in Tuscany (Italy). Polyolefins, poly(styrene) (PS), poly(vinyl chloride) (PVC), polycarbonate (PC), poly(ethylene terephthalate) (PET), and the polyamides poly(caprolactame) (Nylon 6) and poly(hexamethylene adipamide) (Nylon 6,6) were fractionated and quantified through a sequence of selective solvent extractions followed by either analytical pyrolysis or reversed-phase HPLC analysis of the products of hydrolytic depolymerizations under acidic and alkaline conditions.
View Article and Find Full Text PDFIt is well established that most of the plastic pollution found in the oceans is transported via rivers. Unfortunately, the main processes contributing to plastic and debris displacement through riparian systems is still poorly understood. The Marine Litter Drifter project from the Arno River aims at using modern consumer software and hardware technologies to track the movements of real anthropogenic marine debris (AMD) from rivers.
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