Tetra- and hexa-nuclear mercury(II) complexes have been obtained from tetrathiacalix[4]arene and tetramercaptotetrathiacalix[4]arene, respectively, and structurally characterised in the solid state; the complexes provide new digonal and trigonal receptors of the koiland type.
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Koilands from thiophiles: mercury(II) clusters from thiacalixarenes.
Chem Commun (Camb)
May 2002
Laboratoire de Chimie de Coordination Organique, Université Louis Pasteur, F-67000 Strasbourg, France.
Tetra- and hexa-nuclear mercury(II) complexes have been obtained from tetrathiacalix[4]arene and tetramercaptotetrathiacalix[4]arene, respectively, and structurally characterised in the solid state; the complexes provide new digonal and trigonal receptors of the koiland type.
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