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Mesoporous Single-Crystal FeFe(CN)6 Microspheres for Superior Potassium-Ion Storage.
Angew Chem Int Ed Engl
January 2025
Nanjing Normal University, School of Chemistry and Materials Science, CHINA.
Metal hexacyanoferrates (HCFs), also known as Prussian blue analogues, are ideal cathodes for potassium-ion batteries (PIBs) due to their nontoxicity and cost-effectiveness. Nevertheless, obtaining metal HCF cathode materials with both long-term cycling stability and high rate performance remains a daunting challenge. In this study, we present mesoporous single-crystalline iron hexacyanoferrate (MSC-FeHCF) microspheres, featuring a single-crystalline structure that contains interconnected pores spanning the entire crystal lattice.
View Article and Find Full Text PDFBalancing pH and Pressure Allows Boosting Voltage and Power Density for a H-I Redox Flow Battery.
ACS Appl Energy Mater
January 2025
Department of Chemical Engineering, Delft University of Technology, Van der Maasweg 9, 2629HZ Delft, The Netherlands.
The decoupled power and energy output of a redox flow battery (RFB) offers a key advantage in long-duration energy storage, crucial for a successful energy transition. Iodide/iodine and hydrogen/water, owing to their fast reaction kinetics, benign nature, and high solubility, provide promising battery chemistry. However, H-I RFBs suffer from low open circuit potentials, iodine crossover, and their multiphase nature.
View Article and Find Full Text PDFA Highly Sensitive Triple Quad LC-MS/MS Method Development and Validation for the Determination of Bexicaserin (LP352) in Human Plasma and Urine Matrices.
Biomed Chromatogr
February 2025
Department of Clinical Pharmacology and Pharmacometrics, Longboard Pharmaceuticals, Inc. is a part of Lundbeck as a wholly owned subsidiary of Lundbeck LLC, La Jolla, California, USA.
Bexicaserin is a highly selective agonist at the 5-HT receptor in clinical development for the treatment of seizures associated with developmental and epileptic encephalopathies (DEEs). We report an LC-MS/MS method for the quantitative estimation of bexicaserin in human plasma and urine. The sample preparation involves the extraction of bexicaserin and internal standard (CD-bexicaserin; IS) from 150 μL plasma and 50 μL urine using a solid phase extraction method.
View Article and Find Full Text PDFThe effect of introducing fluorine doping and sulfur vacancies on SnS as the anode electrode of LIBs: a density functional theory study.
Phys Chem Chem Phys
January 2025
School of Electromechanical and Information Engineering, PuTian University, Putian Fujian 351100, China.
As the anode material of LIBs, the SnS electrode boasts a reversible specific capacity as high as 1231 mA h g. Additionally, SnS possesses a CdI2-type layered structure with a layer spacing of 0.59 nm, which allows it to accommodate numerous lithium ions and facilitate rapid charge transfer.
View Article and Find Full Text PDFAcid resistance and bond strength of calcium-containing adhesive on ename.
Int Dent J
January 2025
Department of Cariology and Operative Dentistry, Graduate School of Medical and Dental Sciences, Institute of Science Tokyo, Bunkyo-ku, Tokyo, Japan.
Introduction And Aims: Marginal sealing by enamel bonding is important to enhance the durability of the restoration and prevent secondary caries after operative procedure. This study aimed to evaluate the enamel acid resistance and bond strength of an experimental calcium-containing adhesive system.
Methods: All materials were provided by Kuraray Noritake Dental, Inc.
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