The reaction of BiCl(3) with the lithium salt of o-di-tert-butylphenol under nitrogen forms organic oxidation products rather than the expected Bi(OAr)(3) complex, and bismuth disproportionation products. Likewise, the decomposition of Bi(III) aryloxides Bi(O-2,6-(i)Pr(2)C(6)H(3))(3) and ClBi(O-2,4,6-(t)Bu(3)C(6)H(2))(3) leads to corresponding organic oxidation products. These reactions can be explained by Bi-O bond homolysis to form unstable Bi(II) radicals, analogous to a fundamental step suggested to intervene in the SOHIO process.
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[Effect of tetramethylpyrazine on platelet activation and vascular endothelial function in patients with acute coronary syndrome undergoing percutaneous coronary intervention].
Zhongguo Zhong Xi Yi Jie He Za Zhi
December 2007
Department of Cardiology, Jiangxi Provincial People's Hospital, Nanchang.
Objective: To explore the effect of tetramethylpyrazine (TMP) on platelet activation and vascular endothelial function after percutaneous coronary intervention (PCI) in patients with acute coronary syndrome (ACS).
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Evidence for an unstable Bi(II) radical from Bi-O bond homolysis. Implications in the rate-determining step of the SOHIO process.
Inorg Chem
July 2002
Department of Chemistry, Campus Box 298860, Texas Christian University, Fort Worth, Texas 76129, USA.
The reaction of BiCl(3) with the lithium salt of o-di-tert-butylphenol under nitrogen forms organic oxidation products rather than the expected Bi(OAr)(3) complex, and bismuth disproportionation products. Likewise, the decomposition of Bi(III) aryloxides Bi(O-2,6-(i)Pr(2)C(6)H(3))(3) and ClBi(O-2,4,6-(t)Bu(3)C(6)H(2))(3) leads to corresponding organic oxidation products. These reactions can be explained by Bi-O bond homolysis to form unstable Bi(II) radicals, analogous to a fundamental step suggested to intervene in the SOHIO process.
View Article and Find Full Text PDF[Histopathologic features in atherectomy samples obtained from patient with unstable angina, stable angina and restenosis. Directional Atherectomy Lombardi Group].
G Ital Cardiol
June 1996
Istituto di Anatomia Patologica, IRCCS Policlinico San Matteo, Pavia.
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