Convergent enantioselective synthesis of the tricyclic core of phomactin A.

Org Lett

Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215, USA.

Published: July 2002

[reaction: see text] The tricyclic core of phomactin A was synthesized from 6,6-dimethyl-2-cyclohexen-1-one. Key reactions include the addition of a cyclohexenyllithium reagent to an epoxyaldehyde and a regioselective intramolecular epoxide opening to install the oxadecalin core.

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http://dx.doi.org/10.1021/ol026159tDOI Listing

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