Pattern formation in phase-separating gels with spontaneous shear.

Phys Rev Lett

Max-Planck-Institut für Polymerforschung, Postfach 3148, D-55021 Mainz, Germany.

Published: July 2002

We study pattern formation in gels undergoing simultaneous phase separation and orientational ordering. A 2D numerical simulation is performed using a minimal model of nonlinear elasticity with density-anisotropy coupling. For strong positive coupling, the collapsed phase elongates along the phase boundary and buckle, creating a folded structure with paired topological defects. For negative coupling, soft elasticity of the swollen phase causes a droplet morphology as in liquid-liquid phase separation. Their possible realizations in nematic liquid-crystalline gels are discussed.

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http://dx.doi.org/10.1103/PhysRevLett.89.025702DOI Listing

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