Waste tyre rubber can be used as a precursor for the production of high quality activated carbons. However, there is concern that inorganic impurities present in the rubber feed may restrict their use in liquid phase applications with high purity requirements. This paper presents an investigation of the presence and the leaching of inorganic species from activated carbons derived from waste tyre rubber. For the purpose of this work, a number of carbons were produced, characterised for their BET surface area and analysed for their inorganic composition. Subsequently, a number of tests were performed to evaluate the leaching of different inorganic species into solution at various pH values and carbon doses. Results showed that rubber-derived carbons contained elevated concentrations of sulphur and zinc, as well as traces of other metals such as lead, cadmium, chromium and molybdenum. Inorganic levels were significantly affected by production conditions, particularly degree of carbon activation and the nature of the gasification agent. However, leaching tests showed that the availability of these species in neutral pH conditions was very limited. Results demonstrated that, when using carbons doses comparable to those employed in water treatment works, only sulphur levels exceeded, in some occasions, health based quality standards proposed for drinking water.
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http://dx.doi.org/10.1016/s0043-1354(01)00422-5 | DOI Listing |
J Hazard Mater
January 2025
University of Wuppertal, School of Architecture and Civil Engineering, Institute of Foundation Engineering, Water and Waste Management, Laboratory of Soil and Groundwater Management, Pauluskirchstraße 7, Wuppertal 42285, Germany. Electronic address:
Two novel and unique adsorptive materials, one (Fluorolock®) from clay mineral sepiolite coated with the cationic polymer polydiallyldimethylammionium chloride (pDADMAC) and the other (Intraplex®) from colloidal activated carbon were specially developed for the in situ remediation of per- and polyfluoroalkyl substances (PFAS) in the saturated zone. We evaluated the potential of both materials to immobilize PFAS in soils under flow conditions via soil column experiments using groundwater, which was contaminated with PFAS in the field. Furthermore, the potential ecotoxicological effects of both materials on aquatic organisms were assessed by exposing the soil column effluent to Daphnia magna.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
Organic Geochemistry Unit, School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK; School of Geography, University of Bristol, Bristol BS8 1SS, UK.
Plastic mulch films support global food security, however, their composition and the potential release rates of organic, metal and metalloid co-contaminants remains relatively unknown. This study evaluates the low molecular weight organic additives, metal and metalloid content and leaching from low density polyethylene (LDPE) and biodegradable plastic mulch films. We identified 59 organic additives, and non-intentionally added substances in the new LDPE films (39.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Chemical Engineering Materials Environment, Sapienza University of Rome, Via Eudossiana 18, 00184 Rome, Italy.
This study introduces a sustainable approach for enhancing the fire retardancy and smoke suppression of poly(lactic acid) (PLA) composites, contributing to addressing one of the major challenges in biocomposites that limits their application in various engineering fields, as automotive and construction sectors. Flax fibers (FF) were surface functionalized with a novel organic-inorganic hybrid flame retardant (FR), offering a sustainable bioinspired approach that mitigates potential mechanical properties impairment and FR leaching, which can cause environmental concerns and reduced composite durability. The process involves a three-step coating procedure.
View Article and Find Full Text PDFMolecules
January 2025
Department of Inorganic Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Skłodowska University, Maria Curie-Skłodowska Sq. 2, 20-031 Lublin, Poland.
Owing to the intensive development of electrical and electronic equipment, there is an increasing demand for precious metals, which are often used for its production. Due to their scarce supply, it is important to recover them from secondary sources. A promising way to recover precious metals are impregnated resins.
View Article and Find Full Text PDFMolecules
December 2024
School of Resources and Safety Engineering, Wuhan Institute of Technology, Wuhan 430205, China.
As a large-volume industrial solid waste generated during the production of wet-process phosphoric acid, the primary disposal method for phosphogypsum (PG) currently involves centralized stockpiling, which requires substantial land use. Additionally, PG contains impurities, such as phosphorus, fluorine, and alkali metals, that may pose potential pollution risks to the surrounding environment. However, the mechanisms governing the co-release of phosphorus and fluorine impurities alongside valuable metal cations during leaching remain unclear, posing challenges to efficient disposal and utilization.
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