Polymer-supported catalysts: enantioselective hydrogenation and hydrogen transfer reduction.

Bioorg Med Chem Lett

Laboratoire de Catalyse et Synthèse Organique, UMR 5622, Université Claude Bernard Lyon 1, CPE, 43 Bd. du 11 Novembre 1918, 69622 Villeurbanne Cedex, France.

Published: July 2002

Different types of heterogenized catalysts were involved in asymmetric reactions. Hydrogen transfer reduction was performed with amino alcohols derived from poly((S)-(GMA-co-EGDMA or DVB)) and hydrogenation with BINAP grafted onto PEG or copolymerized with isocyanates as ligands. Attempts of catalysts recycling are reported.

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http://dx.doi.org/10.1016/s0960-894x(02)00258-5DOI Listing

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