The recent development of satellite instruments that obtain spectrally resolved measurements of the atmosphere has highlighted the problem of how to determine the best subsets, or microwindows, of such spectra for retrievals of temperature and composition. A technique is described that maximizes the information content (or some other figure of merit) based on the modeling of the propagation of systematic as well as random error terms through the retrieval process. Apart from selecting microwindows, this technique can also prioritize existing microwindows for different circumstances and provides a full error analysis of the retrieval. A practical application is demonstrated for the Michelson Interferometer for Passive Atmospheric Sounding limb-viewing interferometer, but the technique is equally applicable to nadir-viewing instruments.
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http://dx.doi.org/10.1364/ao.41.003665 | DOI Listing |
Anal Chem
March 2022
CAS Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences (CAS), Dalian 116023, China.
Enrichment and identification of phosphopeptides in real biological samples are of great significance in many aspects. Herein, Ti-immobilized silica hollow nanospheres were tailored via chelating with phosphonic acid groups produced from dealkylation of phosphonate ester functionalized silica hollow nanospheres, which were synthesized through a single micelle templated method with diethylphosphatoethyltriethoxysilane (DPTES) and tetramethoxysilane (TMOS) as silane precursors under neutral conditions. The characterization results of transmission electron microscopy (TEM), nitrogen sorption isotherms, FT-IR, and energy-dispersive X-ray (EDX) spectroscopy confirmed the successful preparation of Ti-immobilized silica hollow nanospheres (SHS-Ti; approximately 17 nm particle size), which possessed a 10 nm hollow cavity with 1.
View Article and Find Full Text PDFWe demonstrate the use of ultrafast laser pulses to precisely ablate the side of polymer multicore optical fibres (MCF) in such a way that light is efficiently coupled out of a set of MCF cores to free space. By individually exciting sets of MCF cores, this flexible "micro-window" technology allows the controllable generation of light sources at multiple independently selectable locations along the MCF. We found that the maximum fraction of light that could be side coupled from the MCF varied between 55% and 73%.
View Article and Find Full Text PDFSensors (Basel)
July 2018
State Key Laboratory of Remote Sensing Science, Institute of Remote Sensing and Digital Earth, Chinese Academy of Sciences, Beijing 100101, China.
The Atmospheric Infrared Ultraspectral Sounder (AIUS), the first high-resolution (0.02 cm) solar occultation sounder, aboard GF5, was launched in May 2018 from China. However, relevant studies about vertical profiles of atmospheric constituents based on its operational data were not conducted until half a year later.
View Article and Find Full Text PDFAtmos Chem Phys
September 2012
Jet Propulsion Laboratory, California Institute of Technology Pasadena, California, USA.
We present a detailed description of the TES methanol (CHOH) retrieval algorithm, along with initial global results showing the seasonal and spatial distribution of methanol in the lower troposphere. The full development of the TES methanol retrieval is described, including microwindow selection, error analysis, and the utilization of a priori and initial guess information provided by the GEOS-Chem chemical transport model. Retrieval simulations and a sensitivity analysis using the developed retrieval strategy show that TES: (i) generally provides less than 1.
View Article and Find Full Text PDFAcc Chem Res
February 2011
Department of Chemistry, Texas A&M University, College Station, 77842, United States.
Metal-organic frameworks (MOFs)-highly crystalline hybrid materials that combine metal ions with rigid organic ligands-have emerged as an important class of porous materials. The organic ligands add flexibility and diversity to the chemical structures and functions of these materials. In this Account, we summarize our laboratory's experience in tuning the topology and functionality of MOFs by ligand design.
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