Brillouin-scattering spectra of the molecular glass-forming material propylene carbonate (PC) in the temperature range 140 K to 350 K were analyzed using both the phenomenological Cole-Davidson memory function and a hybrid memory function consisting of the Cole-Davidson function plus a power-law term representing the critical decay part of the fast beta relaxation. The spectra were also analyzed using the extended two-correlator schematic mode-coupling theory (MCT) model recently employed by Götze and Voigtmann to analyze depolarized light backscattering, dielectric, and neutron-scattering spectra of PC [Phys. Rev. E 61, 4133 (2000)]. We assess the ability of the phenomenological and MCT fits, each with three free fitting parameters, to simultaneously describe the spectra and give reasonable values for the alpha-relaxation time tau(alpha).
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1103/PhysRevE.65.051503 | DOI Listing |
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!