A canonical Hamiltonian formulation of the nonlinear Schrödinger equation has been derived in this paper. This formulation governs the dynamics of pulse propagation in a one-dimensional, periodic Kerr medium when the frequency content of the pulse is sufficiently narrow relative to a carrier frequency, and sufficiently far removed from a photonic band gap of the medium. Our Hamiltonian is numerically equal to the energy, and our fields obey canonical commutation relations, so the theory can easily be quantized. We clarify the nature of the conserved quantities associated with simple symmetries.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1103/PhysRevE.65.046601 | DOI Listing |
Entropy (Basel)
December 2024
National Institute for Fusion Science, Oroshi, Toki 509-5292, Gifu, Japan.
A topological constraint, characterized by the Casimir invariant, imparts non-trivial structures in a complex system. We construct a kinetic theory in a constrained phase space (infinite-dimensional function space of macroscopic fields), and characterize a self-organized structure as a thermal equilibrium on a leaf of foliated phase space. By introducing a model of a grand canonical ensemble, the Casimir invariant is interpreted as the number of topological particles.
View Article and Find Full Text PDFPhys Rev E
November 2024
Dipartimento di Scienze Matematiche, Politecnico di Torino, Corso Duca degli Abruzzi 24, Turin, Italy and INFN, Sezione di Torino, Via P. Giuria 1, 10125 Turin, Italy.
The physical significance of the stochastic processes associated to the generalized Gibbs ensembles is scrutinized here with special attention to the thermodynamic fluctuations of small systems. Differently from the so-called stochastic thermodynamics, which starts from stochastic versions of the first and second law of thermodynamics and associates thermodynamic quantities to microscopic variables, here we consider stochastic variability directly in the macroscopic variables. By recognizing the potential structure of the Gibbs ensembles, when expressed as a function of the potential entropy generation, we obtain exact nonlinear thermodynamic Langevin equations (TLEs) for macroscopic variables, with drift expressed in terms of entropic forces.
View Article and Find Full Text PDFPhys Rev E
November 2024
Instituto de Física, Universidade Federal do Rio de Janeiro, Rio de Janeiro, RJ 21941-972, Brazil.
The ultimate goal of this paper is to develop a systematic method for deriving quantum master equations that satisfy the requirements of a completely positive and trace-preserving (CPTP) map, further describing thermal relaxation processes. In this paper, we assume that the quantum master equation is obtained through the canonical quantization of the generalized Brownian motion proposed in our recent paper [T. Koide and F.
View Article and Find Full Text PDFJ Mol Model
October 2024
Departamento de Química, Universidad Autónoma Metropolitana Iztapalapa, Av. San Rafael Atlixco 186, Leyes de Reforma 1Ra Secc, Iztapalapa, 09340, Mexico City, Mexico.
Context: Describing chemical processes at solid-liquid interfaces as a function of a fixed electron chemical potential presents a challenge for electronic structure calculations and is essential for understanding electrochemical phenomena. Grand Canonical Density Functional Theory (GCDFT) allows treating solid-liquid interfaces in such a way that studying the influence of a fixed electron potential arises naturally. In this work, GCDFT is used to compute the adsorption grand potential (AGP), a key parameter for understanding and predicting the behavior of adsorbates on surfaces.
View Article and Find Full Text PDFIEEE Trans Neural Netw Learn Syst
September 2024
Embedding the Hamiltonian formalisms into neural networks (NNs) enhances the reliability and precision of data-driven models, in which substantial research has been conducted. However, these approaches require the system to be represented in canonical coordinates, i.e.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!