The densities of argon metastable (3)P(2), and resonance (1)P(1), (3)P(1) states were measured along a cylindrical magnetron discharge radius by absorption spectroscopy using a narrow bandwidth single mode diode laser. The theoretical treatment includes calculations of the rates of numerous excitation and decay processes based on nonlocal electron kinetics, and analysis of the transport equations for the resonance and metastable atoms. The solution technique of the Biberman-Holstein equation of radiation transport is developed in conformity with magnetron discharge geometry. The radial profile of the effective lifetime is obtained, taking into account radiation escape on the inner and outer electrodes. The distinction in formations of the radial profiles of the resonance and metastable atoms caused by specifics of radiation transport and diffusion is demonstrated. The results of experiments and calculations are compared.
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http://dx.doi.org/10.1103/PhysRevE.65.046401 | DOI Listing |
J Phys Chem Lett
January 2025
Thin film Energy Storage Laboratory, Department of Physics and Nanotechnology, SRM Institute of Science and Technology, Kattankulathur 603 203Tamil Nadu India.
Manganese oxides are a promising cathode material for aqueous zinc-ion batteries (AZIBs), but thin-film configurations remain underexplored. This study investigates the electrochemical dynamics of 60 nm thin MnO thin films, fabricated via RF magnetron reactive sputtering. It addresses the highest reported capacity (25 mAh/g) in thin film form, stability over 500 cycles, effective performance across varying current rates, surpassing previous studies and challenges such as phase stability, and capacity fading over extended cycling, aiming to enhance uniformity, minimizing diffusion barriers for improved performance.
View Article and Find Full Text PDFNanoscale
January 2025
College of Science, China Agricultural University, Beijing, 100083, China.
Aqueous zinc-ion batteries are an appealing electrochemical energy storage solution due to their affordability and safety. Significant attention has been focused on vanadium oxide cathode materials for ZIBs, owing to their high specific capacity, unique layered or tunnel structures, and low cost. Compared to traditional methods for preparing and assembling electrode materials, direct current (DC) magnetron sputtering allows direct synthesis and uniform deposition on current collectors, offering advantages such as simplicity, mild reaction conditions, and strong film adhesion.
View Article and Find Full Text PDFNanoscale
January 2025
Plasma Nanotechnology Laboratory, Physical Sciences Division, Institute of Advanced Study in Science and Technology (IASST), Guwahati-781035, India.
In this work, we report an intuitive magnetron sputtering technique for the synthesis of vertically aligned MoS (v-MS) nanostructures. The morphology and orientation of the as-synthesized nanostructures can be modified by altering the parameters of the sputtering process. This work emphasizes the versatility of magnetron sputtering to synthesize edge-enriched vertically aligned 2D nanostructures.
View Article and Find Full Text PDFThe hypothesis that the antibacterial effect of copper depends on its state was tested. It was studied the antibacterial effect of copper applied to the fabric, copper in chelated and free (ionic) forms on the growth intensity of and in the system after a single or "primary" contact. Classical microbiology methods were used.
View Article and Find Full Text PDFNano Lett
October 2024
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jingshi Road 17923, Jinan 250061, PR China.
Alloy-type anodes used in magnesium ion batteries (MIBs) have garnered significant attention in light of their substantial theoretical specific capacities and possible matchability with conventional electrolytes. However, the major challenges for alloy-type anodes are the sluggish transport kinetics as well as severe volume variations during the discharge/charge processes. Herein, we present a strategy for phase-structure modulation to fabricate a self-supporting In-Bi film through straightforward magnetron sputtering.
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