We report on the first time-dependent close-coupling calculation of dielectronic capture into a doubly excited state of a two-electron atom. An incoming electron is represented by a Gaussian wave packet which collides with singly ionized helium in its ground state. The close-coupling equations describe the propagation of the total compound wave function on a two-dimensional radial lattice. By projecting this wave function onto a doubly excited state of neutral helium, we can determine the probability amplitude for dielectronic capture into one of these states and the subsequent autoionization from it.
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http://dx.doi.org/10.1103/PhysRevLett.88.173004 | DOI Listing |
Philos Trans A Math Phys Eng Sci
August 2023
Pulsed Power Sciences Center, Sandia National Laboratories, Albuquerque, NM 87123, USA.
Modern density functional theory (DFT) is a powerful tool for accurately predicting self-consistent material properties such as equations of state, transport coefficients and opacities in high energy density plasmas, but it is generally restricted to conditions of local thermodynamic equilibrium (LTE) and produces only averaged electronic states instead of detailed configurations. We propose a simple modification to the bound-state occupation factor of a DFT-based average-atom model that captures essential non-LTE effects in plasmas-including autoionization and dielectronic recombination-thus extending DFT-based models to new regimes. We then expand the self-consistent electronic orbitals of the non-LTE DFT-AA model to generate multi-configuration electronic structure and detailed opacity spectra.
View Article and Find Full Text PDFPhys Rev E
June 2017
CEA, DAM, DIF, F-91297 Arpajon, France.
We present the relativistic expressions of standard nonrelativistic microreversibility relations that can be used in collisional-radiative equilibrium models to calculate the transition rates including the free electron degeneracy for collisional excitation and deexcitation, collisional ionization and three-body recombination, dielectronic capture and autoionization, photoexcitation and photodeexcitation, and radiative recombination and photoionization. Semiempirical expressions or more refined calculations can be used for the cross sections of interest as long as they are calculated by taking into account either nonrelativistic, relativistic, or ultrarelativistic effects for both the bound and free electrons. The bound and the free electrons should be treated on the same footing.
View Article and Find Full Text PDFPhys Rev Lett
September 2009
GSI Helmholtzzentrum für Schwerionenforschung, D-64291 Darmstadt, Germany.
The Breit interaction typically appears as a-more or less small-correction to the Coulomb repulsion acting among the electrons. We here propose two x-ray measurements on the angular distribution and linear polarization of the 1s2s(2)2p(1/2) J=1-->1s(2)2s(2) J=0 electric-dipole radiation of high-Z, beryllium-like ions, following the resonant electron capture into initially lithium-like ions, for which the Breit interaction strongly dominates the Coulomb repulsion and leads to a qualitative change in the expected x-ray emission pattern. The proposed measurements are feasible with present-day x-ray detectors and may serve a stringent test on relativistic corrections to the electron-electron interaction in the presence of strong fields.
View Article and Find Full Text PDFPhys Rev Lett
August 2003
Institut für Kernphysik, Justus-Liebig-Universität, D-35392 Giessen, Germany.
The 2s(1/2)-2p(1/2) energy splittings DeltaE(L) of the lithiumlike ions 19779Au76+, 20882Pb79+, and 23892U89+ have been measured at the Experimental Storage Ring, utilizing low energy dielectronic recombination. The resonance energies in total 41 different 1s(2) 2p(1/2)nl(j(')) (n > or =20) autoionizing Rydberg states populated in the dielectronic capture process have been determined. The 2s(1/2)-->2p(1/2) excitation energies have been obtained by extrapolation of these resonance energies to the associated series limits n--> infinity.
View Article and Find Full Text PDFPhys Rev Lett
April 2002
Department of Physics, Rollins College, Winter Park, Florida 32789, USA.
We report on the first time-dependent close-coupling calculation of dielectronic capture into a doubly excited state of a two-electron atom. An incoming electron is represented by a Gaussian wave packet which collides with singly ionized helium in its ground state. The close-coupling equations describe the propagation of the total compound wave function on a two-dimensional radial lattice.
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