Ideal nanowire interconnects for nanoelectronics will be refractory, covalently bonded, and highly conductive, irrespective of crystallographic orientation. Theoretical studies suggest that boron nanotubes should be stable and exhibit higher electrical conductivities than those of carbon nanotubes. We describe CVD growth of elemental boron nanowires, which are found to be dense nanowhiskers rather than nanotubes. Conductivity measurements establish that they are semiconducting, with electrical properties consistent with those of elemental boron. High conductivities should be achievable through doping.
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http://dx.doi.org/10.1021/ja017817s | DOI Listing |
Exploring the effects of electron donor (D) and acceptor (A) functional groups in tuning the condensed state properties has been a challenging yet efficient approach to reveal promising materials for cutting-edge applications. Herein, a series of boron-nitrogen (BN) incorporated organic congeners (NBNMe2, NBOMe, NBF, NBCl, NBBr, NBCN, NBPy) appended with functional groups having various degrees of D/A characteristics were developed and their potential in controlling supramolecular assembly and condensed state luminescence features (>90 nm redshift in ) was explored. Despite the minor structural engineering in BN-based small molecules, they effectively modulated conformational orientation and molecular packing, leading to the directed growth of distinct and highly ordered self-assembly patterns, , nanosheets, nanospheres, nanowires, and nanorods.
View Article and Find Full Text PDFNat Commun
March 2025
College of Chemistry and Molecular Sciences, Institute for Advanced Studies (IAS), Wuhan University, Wuhan, P. R. China.
Biomass valorization is a way to promote the 'waste-to-wealth' concept, which is a pre-requisite condition for a future sustainable lifestyle. The direct utilization of natural polymer for value-added materials should be prioritized. With this object, we demonstrate a facile and economical method to prepare chitin-derived supramolecular nanowires-stabilized single-atom sites Pt catalysts (SS-Pt-CSNs).
View Article and Find Full Text PDFFood Chem
February 2025
State Key Laboratory of Food Nutrition and Safety, Tianjin University of Science and Technology, Tianjin 300457, China; Tianjin Key Laboratory of Food Science and Health, School of Medicine, Nankai University, Tianjin 300071, China. Electronic address:
Enrofloxacin (ENR) residues in animal derived foods are harmful to human health. A molecularly imprinted electrochemiluminescence sensor was constructed for ENR detection utilizing a self-enhanced quasi-three-dimensional luminescent-composite of boron nitride quantum dots/nitrogen-doped mesoporous carbon crosslinked with copper nanowires (BNQDs/NMC-CuNWs). One-dimensional CuNWs with near-infrared electrochemiluminescence (NIR-ECL) properties were inserted into the electroactive layer of two-dimensional NMC to form quasi-three-dimensional NMC-CuNWs, which inhibited the aggregation of CuNWs and increased the electron and active ion transport rates.
View Article and Find Full Text PDFNanomaterials (Basel)
January 2025
Theoretical Physics, Institute of Physics, Chemnitz University of Technology, D-09107 Chemnitz, Germany.
Using gradient-corrected density functional theory we investigate the mechanical properties of ultrathin boron (B) and phosphorus (P) doped silicon nanowires (SiNWs) along the [001] and [111] orientations within the PBE approximation. Both pristine and doped SiNWs under study have diameters ranging from 5 to 8 Å. Our results show that doping significantly enhances the bulk modulus (B0), shear modulus (GV), Young's modulus (), and other mechanical parameters.
View Article and Find Full Text PDFNanomicro Lett
October 2024
State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, People's Republic of China.
With vigorous developments in nanotechnology, the elaborate regulation of microstructure shows attractive potential in the design of electromagnetic wave absorbers. Herein, a hierarchical porous structure and composite heterogeneous interface are constructed successfully to optimize the electromagnetic loss capacity. The macro-micro-synergistic graphene aerogel formed by the ice template‑assisted 3D printing strategy is cut by silicon carbide nanowires (SiC) grown in situ, while boron nitride (BN) interfacial structure is introduced on graphene nanoplates.
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