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Synthesis of 2,3-disubstituted indole using palladium(II)-catalyzed cyclization with alkenylation reaction. | LitMetric

The reaction of ethyl 2-ethynylphenylcarbamate derivative with alkenes in the presence of a palladium(II) catalyst, copper dichloride and tetrabutylammonium fluoride (TBAF) produced 2-substituted 3-ethenylindoles during refluxing. The intramolecular cyclization reaction of ethyl 2-ethynylphenylcarbamates, which have an ethenyl part in the ethynyl group, was also used to produce carbazole derivatives.

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http://dx.doi.org/10.1248/cpb.50.235DOI Listing

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