Bis(mu-2-cyanopyridine-N:N')bis[(2-cyanopyridine-N)silver(I)] bis(tetrafluoroborate): an anion-linked molecular ladder.

Acta Crystallogr C

School of Chemistry, The University of Nottingham, University Park, Nottingham NG7 2RD, England.

Published: November 2001

In the title compound, [Ag(2)(C(6)H(4)N(2))(4)](BF(4))(2), the Ag(I) cations adopt distorted trigonal-planar coordination geometries. The Ag(I) centres are linked via two bridging 2-cyanopyridine ligands to give a centrosymmetric dinuclear complex in which the Ag(I) coordination environment is completed by monodentate non-bridging 2-cyanopyridine ligands. Bridging Ag...F(BF(2))F...Ag interactions link the dinuclear cations into molecular ladders.

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http://dx.doi.org/10.1107/s0108270101013956DOI Listing

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