High-resolution photoemission is used to study the electronic structure of the cuprate superconductor, Bi(2)Sr(2)CaCu(2)O(8+delta), as a function of hole doping and temperature. A kink observed in the band dispersion in the nodal line in the superconducting state is associated with coupling to a resonant mode observed in neutron scattering. From the measured real part of the self-energy it is possible to extract a coupling constant which is largest in the underdoped regime, then decreasing continuously into the overdoped regime.
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http://dx.doi.org/10.1103/PhysRevLett.87.177007 | DOI Listing |
Nat Commun
January 2025
School of Mechatronical Engineering, Beijing Institute of Technology, Beijing, 100081, China.
Designing asymmetrical structures is an effective strategy to optimize metallic catalysts for electrochemical carbon dioxide reduction reactions. Herein, we demonstrate a transient pulsed discharge method for instantaneously constructing graphene-aerogel supports asymmetric copper nanocluster catalysts. This process induces the convergence of copper atoms decomposed by copper chloride onto graphene originating from the intense current pulse and high temperature.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China.
Selective catalytic reduction of NO by NH(NH-SCR) remains challenging for diesel vehicles due to the complex exhaust condition. Cu-SAPO-18 zeolite has emerged as an efficient catalyst for the NH-SCR process, attributed to its unique small pore configuration and high NH-SCR activity. Herein, Zr-modified Cu-SAPO-18 has been fabricated and evaluated for the reduction of NO.
View Article and Find Full Text PDFLangmuir
January 2025
Federal University of Itajubá, Itajubá-MG 37500-903, Brazil.
CuO/CeO and CuO/CeO-LaO catalysts, synthesized with varying CeO and LaO molar ratios (1:1, 1:2, and 2:1), were prepared via the hydrothermal method and tested in the water-gas shift reaction (150-350 °C). LaO addition altered structural properties, reducing surface area and copper dispersion. XANES and in situ XRD confirmed metallic Cu species during reduction and reaction.
View Article and Find Full Text PDFJ Mol Model
January 2025
College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, People's Republic of China.
Context: The rotating arc plasma technique for the synthesis of nitrogen-doped graphene capitalizes on the distinctive attributes of plasma, presenting a straightforward, efficient, and catalyst-free strategy for the production of nitrogen-doped graphene. However, experimental outcomes generally fail to elucidate the atomic-level mechanism behind this process. Our research utilizes molecular dynamics simulations to explore theoretically the formation of radicals during the plasma-driven reaction between methane (CH₄) and nitrogen (N₂).
View Article and Find Full Text PDFACS Nano
January 2025
John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138, United States.
Silicon carbide (SiC) is a semiconductor used in quantum information processing, microelectromechanical systems, photonics, power electronics, and harsh environment sensors. However, its high-temperature stability, high breakdown voltage, wide bandgap, and high mechanical strength are accompanied by a chemical inertness, which makes complex micromachining difficult. Photoelectrochemical (PEC) etching is a simple, rapid means of wet processing SiC, including the use of dopant-selective etch stops that take advantage of the mature SiC homoepitaxy.
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