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Palladium/Benzoic Acid-Catalyzed Regio- and Stereoselective Polymerization of Internal Diynes and Diols through C(sp)-H Activation.
ACS Macro Lett
September 2019
State Key Laboratory of Luminescent Materials and Devices, Center for Aggregation-Induced Emission, South China University of Technology, Guangzhou 510640, China.
The C-H activation has been a hot research area in organic chemistry, and the most difficult one is the C(sp)-H activation. Although the C-H activation has been introduced to the research of synthetic polymer chemistry, the polymerization developed based on C(sp)-H activation is rarely reported, which will enrich the tools for the preparation of functional polymers. In this work, palladium/benzoic acid catalyzed polymerization of internal diynes and diols through C(sp)-H activation was successfully established.
View Article and Find Full Text PDFPalladium/Benzoic Acid Catalyzed Hydroamination of Alkynes.
J Org Chem
June 1999
Research Center for Organic Resources and Materials Chemistry, Institute for Chemical Reaction Science, and Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan.
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