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Non-linear enhancement of ultrafast X-ray diffraction through transient resonances.
Nat Commun
January 2025
SLAC National Accelerator Laboratory, Stanford PULSE Institute, Menlo Park, CA, USA.
Diffraction-before-destruction imaging with ultrashort X-ray pulses can visualize non-equilibrium processes, such as chemical reactions, with sub-femtosecond precision in the native environment. Here, a nanospecimen diffracts a single X-ray flash before it disintegrates. The sample structure can be reconstructed from the coherent diffraction image (CDI).
View Article and Find Full Text PDFLaser Flash Photolysis of Carbazole in Solution: Cation Radical as a Source of Carbazolyl Radical.
J Phys Chem B
January 2025
Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznanskiego 8, 61-614 Poznan, Poland.
In the course of 266 nm nanosecond laser flash photolysis of carbazole (CBL) in acetonitrile, we discovered a new transient absorption band centered at 360 nm that has been heretofore unreported despite numerous reports on similar topics. To put some limits on possible transients responsible for this absorption band and thus to solve the mechanism of CBL photolysis, we employed the strategy of selectively blocking the CBL active sites by various modifications in the structure. This strategy was supported by the use of the solvent effect and triplet quenching by molecular oxygen.
View Article and Find Full Text PDFFrom Waste to Worth: Upcycling Plastic into High-Value Carbon-Based Nanomaterials.
Polymers (Basel)
December 2024
Green Technology Group, Faculty of Science, Alexandria University, Alexandria 21511, Egypt.
Plastic waste (PW) presents a significant environmental challenge due to its persistent accumulation and harmful effects on ecosystems. According to the United Nations Environment Program (UNEP), global plastic production in 2024 is estimated to reach approximately 500 million tons. Without effective intervention, most of this plastic is expected to become waste, potentially resulting in billions of tons of accumulated PW by 2060.
View Article and Find Full Text PDFSingle GAF Domain Phytochrome Exhibits a pH-Dependent Shunt on the Millisecond Timescale.
Chemphyschem
January 2025
Institute of Physical and Theoretical Chemistry, Goethe University Frankfurt am Main, Max-von-Laue-Straße 7, 60438, Frankfurt, Germany.
The light-sensing activity of phytochromes is based on the reversible light-induced switching between two isomerization states of the bilin chromophore. These photo-transformations may not necessarily be only unidirectional, but could potentially branch back to the initial ground state in a thermally driven process termed shunt. Such shunts have been rarely reported, and thus our understanding of this process and its governing factors are limited.
View Article and Find Full Text PDFPhase Change Materials for Energy Storage Applications from PEG and PBAT with AlN and CNT as Fillers.
ACS Omega
December 2024
Department of Intelligent Energy and Industry, Chung-Ang University, Seoul 06974, Republic of Korea.
This study investigates the fabrication of phase change material-poly(butylene adipate--terephthalate) (PCM-PBAT) composites through melt blending techniques, focusing on the impact of isophorone diisocyanate (IPDI) treatment on carbon nanotubes (CNTs) and (3-aminopropyl)triethoxysilane (APTES) treatment on aluminum nitride (AlN) particles. Analysis of mechanical properties highlights an enhancement in tensile strength with APTES-treated AlN particles, while dynamic mechanical analysis (DMA) reveals an increase in stiffness. Laser flash analysis (LFA) investigation demonstrates a significant increase, up to 325%, in thermal conductivity compared to PCM-PBAT composites without filler.
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