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Intrinsic and Extrinsic Photogalvanic Effects in Twisted Bilayer Graphene.
Phys Rev Lett
December 2024
Donostia International Physics Center, Paseo Manuel de Lardizabal 4, 20018 Donostia-San Sebastian, Spain.
The chiral lattice structure of twisted bilayer graphene with D_{6} symmetry allows for intrinsic photogalvanic effects only at off-normal incidence, while additional extrinsic effects are known to be induced by a substrate or a gate potential. In this Letter, we first compute the intrinsic effects and show they reverse sign at the magic angle, revealing a band inversion at the Γ point. We next consider different extrinsic effects, showing how they can be used to track the strengths of the substrate coupling or electric displacement field.
View Article and Find Full Text PDFThe intriguing role of L-cysteine in the modulation of chiroplasmonic properties of chiral gold nano-arrows.
Nanoscale
January 2025
Sorbonne Université, MONARIS, CNRS-UMR 8233, 4 Place Jussieu, F-75005 Paris, France.
Developing chiral plasmonic nanostructures represents a significant scientific challenge due to their multidisciplinary potential. Observations have revealed that the dichroic behavior of metal plasmons changes when chiral molecules are present in the system, offering promising applications in various fields such as nano-optics, asymmetric catalysis, polarization-sensitive photochemistry and molecular detection. In this study, we explored the synthesis of plasmonic gold nanoparticles and the role of cysteine in their chiroplasmonic properties.
View Article and Find Full Text PDFNucleophilic addition of bulk chemicals with imines using N-functionalized hydroxylamine reagents as precursors.
Nat Commun
January 2025
College of Chemistry, Central China Normal University (CCNU), Wuhan, Hubei, PR China.
C-C and C-X bond forming reactions are essential tools in organic synthesis, constantly revolutionizing human life. Among the key methods for constructing new chemical bonds are nucleophilic addition reactions involving imines. However, the inherent challenges in synthesizing and storing imines have stimulated interest in designing stable precursors, which generates imines in situ during the reaction.
View Article and Find Full Text PDFTopolectrical space-time circuits.
Nat Commun
January 2025
Key Laboratory of advanced optoelectronic quantum architecture and measurements of Ministry of Education, Beijing Institute of Technology, Beijing, China.
Topolectrical circuits have emerged as a pivotal platform for realizing static topological states that are challenging to construct in other systems, facilitating the design of robust circuit devices. In addition to spatial dimensionality, synergistic engineering of both temporal and spatial degrees in circuit networks holds tremendous potential across diverse technologies, such as wireless communications, non-reciprocal electronics and dynamic signal controls with exotic space-time topology. However, the realization of space-time modulated circuit networks is still lacking due to the necessity for flexible modulation of node connections in both spatial and temporal domains.
View Article and Find Full Text PDFPhotoinduced Regiodivergent and Enantioselective Cross-Coupling of Glycine Derivatives with Hydrocarbon Feedstocks.
J Am Chem Soc
January 2025
Key Laboratory of Chemical Biology of Fujian Province, iChEM, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, China.
Regiodivergent asymmetric synthesis represents a transformative strategy for the efficient generation of structurally diverse chiral products from a single set of starting materials, significantly enriching their enantiomeric composition. However, the design of radical-mediated regiodivergent and enantioselective reactions that can accommodate a wide range of functional groups and substrates has posed significant challenges. The obstacles primarily lie in switching the regioselectivity and achieving high enantiodiscrimination, especially when dealing with high-energy intermediates.
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