In 1888 the Austrian botanist F. Reinitzer made the observation that the solid compound cholesteryl-benzoate changes - when melting at 145.5 oC - into a cloudy liquid, that however, turns into a clear liquid at 178.5 oC and higher temperatures. The cloudy liquid seemed to be doubly refracting. Soon a number of these so-called 'liquid crystals' were discovered; in 1908 D. Vorländer, professor of organic chemistry at Halle, described more than 250 of these substances. It was O. Lehmann, professor of physics at Aachen (1885), Dresden (1888) and Karlsruhe (1889), who immediately after Reinitzer's observation began a systematic study of these liquid crystals. In The Netherlands the Amsterdam professor of physican chemistry H. W. Bakhuis Roozeboom was interested in liquid crystals, in particular because of their place in his phase system. F.M. Jaeger, at that time teaching chemistry in a secondary school in Zaandam (near Amsterdam) and working as an unpaid university lecturer at the Amsterdam university (by recommendation of Bakhuis Roozeboom), investigated liquid crystals (1906), as did a number of doctoral students (A.C. de Kock, 1903; A. Prins, 1907). At the university of Utrecht L.S. Ornstein, professor of physics, gave the study of liquid crystals a prominent place in his research programme. The discovery of liquid crystals, which seemed to be able to grow, move, divide, copulate, and so on, led to a discussion on the nature of these substances. Time and again Lehmann called them 'apparently living crystals', although without considering them as 'real living beings'. In his book Flüssige Kristalle und die Theorien des Lebens (1906), Lehmann proved to be an obvious adherent of the monistic views of the biologist E. Haeckel. Haeckel considered the existence of liquid crystals as proof of the unity between the inorganic and the organic world that he believed in so strongly. In his last book, Kristallseelen. Studien über das Anorganische Leben (1917), he considered liquid crystals a real form of life, as did F. Rinne, professor of mineralogy and petrography, as late as in the nineteen thirties.
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Soft Matter
January 2025
Dipartimento di Chimica e Chimica Industriale, University of Pisa, via Moruzzi 13, Pisa 56124, Italy.
In the field of chiral smectic liquid crystals, orthoconic antiferroelectric liquid crystals (OAFLCs) have attracted the interest of the scientific community due to the very high tilt angle, close to 45°, and the consequent optical properties. In the present study, the first H NMR investigation is reported on two samples, namely 3F5HPhF9 and 3F7HPhF8, showing the phase sequence isotropic-SmC*-SmC* and the phase sequence isotropic-SmA-SmC*-SmC*, respectively, when cooling from the isotropic to the crystalline phases. To this aim, the liquid crystals were doped with a small amount of deuterated probe biphenyl-4,4'-diol-d.
View Article and Find Full Text PDFWe provide the first direct experimental evidence for the reorientation of liquid crystals by polarized radiation from a conventional, low power, oscillator-based terahertz time-domain spectrometer. Using a terahertz pump - optical probe setup, we observed that the reorientation occurs locally through the resonant amplification of the terahertz field in a specially designed planar metamaterial, adjacent to the liquid crystal layer, and increases with increasing incident terahertz intensity. Our work thus demonstrates that it is possible to induce strong optical nonlinearity in liquid crystals in the terahertz part of the spectrum, paving the way toward the development of new all-optical active terahertz devices as well as electric field sensors for localized resonant systems.
View Article and Find Full Text PDFSoft Matter
January 2025
Department of Physics, Kyoto University, Kyoto 606-8502, Japan.
This study explores the influence of charge distribution and molecular shape on the stability of ferroelectric nematic liquid crystalline phases through atomistic simulations of DIO molecules. We demonstrate the role of dipole-dipole interactions and molecular shape in achieving polar ordering by simulating charged and chargeless topologies, and analysing positional and orientational pair-distribution functions. The charged DIO molecules exhibit head-to-tail and side-by-side parallel alignments conducive to long-range polar order, whereas the chargeless molecules show no polar ordering.
View Article and Find Full Text PDFSmall
January 2025
Department of Chemical Engineering, POSTECH, Pohang, 37673, Republic of Korea.
Liquid crystals (LCs) are widely used as promising stimuli-responsive materials due to their unique combination of liquid and crystalline properties, providing the capability to sense even molecular-scale events and amplify them into macroscopic optical outputs. However, encoding a high level of selectivity to a specific intermolecular event remains a key challenge, leading to prior studies regarding chemically functionalized LC interfaces. Herein, we propose an integrative strategy to significantly advance the design of chemo-responsive LCs through a deep fundamental understanding on the orientational coupling of LCs with new functional molecules, organic ionic plastic crystals (OIs), presented at LC interfaces.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Henan University of Technology, School of Chemistry and Chemical Engineering, CHINA.
Developing of molecular crystalline materials with light-induced multiple dynamic deformation in space dimension and photochromism on time scales has attracted much attention for its potential applications in actuators, sensoring and information storage. Nevertheless, organic crystals capable of both photoinduced dynamic effects and static color change are rare, particularly for multi-component cocrystals system. In this study, we first report the construction of charge transfer co-crystals allows their light-induced solid-to-liquid transition and photochromic behaviors to be controlled by trans-stilbene (TSB) as an electron donor and 3,4,5,6-Tetrafluorophthalonitrile (TFP) as an electron acceptor.
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