The reported ground-state band of 235(92)U143 extending from J = 7/2- to 51/2- is found to be two intercalated bands, one beginning with 7/2- and the other with 9/2-, each with DeltaJ = 2. Analysis by the two-resonating-cluster model leads to 3875 Da.fm2 for the moment of inertia for the first few levels, then increasing by centrifugal stretching. This value is interpreted by the structure p70n112 for the central sphere with clusters p11n16 and p11n15 with radius of revolution R = 8.55 fm. The major principal axis of the Poinsot ellipsoid is taken to be determined by an unquantized number K, with vector intermediate in orientation between L and J. The values of K are found by empirical analysis to equal L + 0.28, with the theory of rotation of the ellipsoid giving L + 0.28 for 7/2-, slowly decreasing to L + 0.251 for 51/2-. The 7/2- band is based on odd values of L (negative parity) and the 9/2- band on even values (positive parity). Negative parity for both bands is achieved by symmetric resonance of the two dissimilar clusters in the 7/2- band and antisymmetric resonance in the 9/2- band.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC46834 | PMC |
http://dx.doi.org/10.1073/pnas.90.13.5901 | DOI Listing |
Nanomaterials (Basel)
January 2025
Department of Physics and Natural Science Research Institute, University of Seoul, Seoul 02504, Republic of Korea.
Bulk n-type SrTiO (STO) has long been known to possess a superconducting ground state at an exceptionally dilute carrier density. This has raised questions about the applicability of the BCS-Eliashberg paradigm with its underlying adiabatic assumption. However, recent experimental reports have set the pairing gap to the critical temperature (Tc) ratio at the BCS value for superconductivity in Nb-doped STO, even though the adiabaticity condition the BCS pairing requires is satisfied over the entire superconducting dome only by the lowest branch of optical phonons.
View Article and Find Full Text PDFSci Rep
January 2025
Applied Optics Laboratory, Institute of Optics and Precision Mechanics, University Setif 1, Setif, 19000, Algeria.
This prediction evaluates the different physical characteristics of magnetic materials XFeO (X = Mg, Ca and Sr) by using density functional theory (DFT). The generalized gradient approximation (GGA) approach is chosen to define the exchange and correlation potential. The structural study of the compounds XFeO (X = Mg, Ca and Sr) shows that the ferromagnetic phase is the more stable ground state, where all the parameters of the network are given at equilibrium.
View Article and Find Full Text PDFPhotochem Photobiol Sci
January 2025
CQC-IMS, Department of Chemistry, University of Coimbra, 3004-535, Coimbra, Portugal.
Solvatochromism exhibited by azobenzene-4-sulfonyl chloride (here abbreviated as Azo-SCl) has been investigated in a series of non-polar, polar-aprotic and polar-protic solvents. The UV-vis spectra of Azo-SCl exhibit two long-wavelength bands, observed at 321-330 nm (band-I) and 435-461 nm (band-II), which are ascribed to the π*-π (S ← S) and π*-n (S ← S) transitions, respectively. The shorter wavelength band indicates a reversal in solvatochromism, from negative to positive solvatochromism, for a solvent with a dielectric constant of 32.
View Article and Find Full Text PDFLight Sci Appl
January 2025
Key Laboratory for Special Functional Materials of Ministry of Education, National & Local Joint Engineering Research Center for High-efficiency Display and Lighting Technology, Henan University, 475004, Kaifeng, China.
Solution-processed quantum dot light-emitting diodes (QLEDs) hold great potential as competitive candidates for display and lighting applications. However, the serious energy disorder between the quantum dots (QDs) and hole transport layer (HTL) makes it challenging to achieve high-performance devices at lower voltage ranges. Here, we introduce "giant" fully alloy CdZnSe/ZnSeS core/shell QDs (size ~ 19 nm) as the emitting layer to build high-efficient and stable QLEDs.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
King Abdullah University of Science and Technology (KAUST), Physical Science and Engineering Division (PSE), Thuwal 23955-6900, Saudi Arabia.
Employing density functional theory for ground state quantum mechanical calculations and the non-equilibrium Green's function method for transport calculations, we investigate the potential of CdS, ZnS, CdZnS, and ZnCdS as tunnel barriers in magnetic tunnel junctions for spintronics. Based on the finding that the valence band edges of these semiconductors are dominated by p orbitals and the conduction band edges by s orbitals, we show that symmetry filtering of the Bloch states in magnetic tunnel junctions with Fe electrodes results in high tunneling magnetoresistances and high spin-polarized current (up to two orders of magnitude higher than in the case of the Fe/MgO/Fe magnetic tunnel junction).
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!