We present the first study of nonlinear optical third-harmonic generation (THG) in the strongly correlated charge-transfer insulator Sr(2)CuO(2)Cl(2). For fundamental excitation in the near infrared, the THG spectrum reveals a strongly resonant response for photon energies near 0.7 eV. Polarization analysis reveals this novel resonance to be only partially accounted for by three-photon excitation to the optical charge-transfer exciton, and indicates that an even-parity state at 2 eV, with a(1g) symmetry, participates in the third-harmonic susceptibility.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1103/PhysRevLett.87.127006 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Quantitative analysis on the optical kerr impact and third harmonic generation in beltrami-shaped curved graphene.
Sci Rep
January 2025
Preparatory Institute for Engineering Studies of Kairouan, (I.P.E.I.K) University of Kairouan, Kairouan, Tunisia.
We present a comprehensive analysis of the optical attributes of graphene sheets with charge carriers residing on a curved substrate. In particular, we focus on the fascinating case of Beltrami geometry and provide an explicit parametrization for this curved two-dimensional surface. By employing the massless Dirac description that is characteristic of graphene, we investigate the impact of the curved geometry on the optical properties within the sample.
View Article and Find Full Text PDF2D Chiral Ag(I) Complexes with A-π-- and D-π--Type Dicarboxylic Acid Ligands: Presenting Significant Differences in Nonlinear Optical Responses.
Inorg Chem
January 2025
Henan Provincial Key Laboratory of Surface and Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450002, P. R. China.
Three two-dimensional (2D) chiral Ag(I) complexes with formulas [Ag(L)(5-nipa)] (), [Ag(L)(5-nipa)] (), and {[Ag(L)(5-hipa)]·2HO} () were prepared through the reactions of AgO with enantiopure -monodentate N-donors (L/L) and different dicarboxylic acids bearing A (acceptor)-π-- and D (donor)-π--type structural features, where / = (-)/(+)-2-(4'-pyridyl)-4,5-pinene-pyridine, 5-Hnipa = 5-nitroisophthalic acid, and 5-Hhipa = 5-hydroxyisophthalic acid. A study of their nonlinear optical responses reveals that chiral and enantiomeric pairs with the A-π--type dicarboxylic acid ligand simultaneously display second- and third-harmonic generation (SHG and THG) responses, while chiral containing the D-π--type dicarboxylic acid ligand only exhibits a very strong THG response. The THG intensity of is 451 × α-SiO, being about 27 and 24 times larger than those of and , respectively.
View Article and Find Full Text PDFStrategies to enhance THz harmonic generation combining multilayered, gated, and metamaterial-based architectures.
Light Sci Appl
January 2025
Department of Physics, University of Ottawa, Ottawa, ON, K1N 6N5, Canada.
Graphene has unique properties paving the way for groundbreaking future applications. Its large optical nonlinearity and ease of integration in devices notably makes it an ideal candidate to become a key component for all-optical switching and frequency conversion applications. In the terahertz (THz) region, various approaches have been independently demonstrated to optimize the nonlinear effects in graphene, addressing a critical limitation arising from the atomically thin interaction length.
View Article and Find Full Text PDFComparative study of third harmonic generation in carbon and silicene nanotubes under magnetic fields.
Sci Rep
December 2024
Department of physics, Faculty of Science, Malayer University, Malayer, Iran.
This study investigates the optical properties of carbon nanotubes (CNTs) and silicene nanotubes (SiNTs) under the influence of external magnetic fields, focusing on their linear and nonlinear optical responses. A tight-binding model is employed to analyze the effects of magnetic fields on the electronic band structure, dipole matrix elements, and various optical susceptibilities of zigzag CNTs and SiNTs. The results reveal significant magnetic field-induced modifications in both linear and nonlinear optical spectra.
View Article and Find Full Text PDFUltrafast Permittivity Engineering Enables Broadband Enhancement and Spatial Emission Control of Harmonic Generation in ZnO.
ACS Photonics
December 2024
Advanced Research Center for Nanolithography, Science Park 106, 1098 XG, Amsterdam, The Netherlands.
Moderate efficiencies of nonlinear optical processes can be one of the challenges limiting even more widespread applications. Here we demonstrate a broadband and giant enhancement of nonlinear processes in ZnO through ultrafast permittivity engineering. A remarkable enhancement of the second and third harmonic generation of up to 2 orders of magnitude can be observed over a broadband range of driving wavelengths.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!