A bioactivity-directed fractionation of the ethanolic extracts of Robinia pseudoacacia L. (Fabaceae) afforded robinlin (1), a novel homo-monoterpene. The structure of 1 was elucidated by spectral analyses of the parent compound as well as its derivatives; 1 showed strong bioactivity in the brine shrimp lethality test (BST).
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First synthesis of (+/-)-robinlin.
Biosci Biotechnol Biochem
September 2004
Department of Biosystems Science, Graduate School of Science and Technology, Kobe University, Rokkodai, Nada-ku, Japan.
The first synthesis of (+/-)-robinlin (1), a novel homo-monoterpene with strong bioactivity in the brine shrimp lethality test, was achieved by starting from 3-isobutyloxy-2,6,6-trimethyl-2-cyclohexen-1-one (2).
View Article and Find Full Text PDFRobinlin: a novel bioactive homo-monoterpene from Robinia pseudoacacia L. (Fabaceae).
Bioorg Med Chem Lett
October 2001
Department of Medicinal Chemistry and Molecular Pharmacology, School of Pharmacy and Pharmacal Sciences, School of Science, Purdue University, West Lafayette, IN 47907, USA.
A bioactivity-directed fractionation of the ethanolic extracts of Robinia pseudoacacia L. (Fabaceae) afforded robinlin (1), a novel homo-monoterpene. The structure of 1 was elucidated by spectral analyses of the parent compound as well as its derivatives; 1 showed strong bioactivity in the brine shrimp lethality test (BST).
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