Pesticides with N,N-dimethyl and thiomethyl moieties (aminocarb, methiocarb and fenthion) were irradiated under artificial light (lambda > 290 nm) in an amorphous wax phase from Persica laevis DC. The effect of the presence of the wax on the photolysis rate differed in the three pesticides, increasing it in aminocarb, having little effect in methiocarb and slowing it down in fenthion. The presence of the wax affected the qualitative photodegradation behaviour of all the pesticides. The data obtained were compared with those for pirimicarb, which had been studied earlier.
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http://dx.doi.org/10.1002/ps.329 | DOI Listing |
Pest Manag Sci
June 2001
Dipartimento di Tossicologia dell'Università, via Ospedale 72, 09124 Cagliari, Italy.
Pesticides with N,N-dimethyl and thiomethyl moieties (aminocarb, methiocarb and fenthion) were irradiated under artificial light (lambda > 290 nm) in an amorphous wax phase from Persica laevis DC. The effect of the presence of the wax on the photolysis rate differed in the three pesticides, increasing it in aminocarb, having little effect in methiocarb and slowing it down in fenthion. The presence of the wax affected the qualitative photodegradation behaviour of all the pesticides.
View Article and Find Full Text PDFElectrophoresis
November 1999
Department of Analytical Chemistry, Faculty of Sciences, University of Córdoba, Spain.
A method for the simultaneous separation and determination of N-methylcarbamate pesticides and their hydrolytic metabolites by micellar electrokinetic chromatography (MEKC) was developed. A mixture of five pesticides (carbaryl, propuxur, carbofuran, aminocarb, and methiocarb) and their corresponding phenols was studied to optimize the separation of its components in terms of various electrophoretic parameters such as buffer type, pH and concentration, sodium dodecyl sulfate concentration, injection conditions, and applied voltage. Excellent separation of all ten analytes was achieved within about 20 min.
View Article and Find Full Text PDFA simplified and sensitive method for the analysis of eight carbamate insecticide residues in foliage, forest soil and fish tissue by direct gas-liquid chromatography (GLC) is described. After fortification, the carbamate residues were extracted from the natural substrates by homogenization in ethyl acetate. The interfering co-extratives present in the crude extracts were removed by filtration through Whatman GF/A glass microfibre after coagulation.
View Article and Find Full Text PDFA rapid and sensitive analytical technique to quantify carbamate insecticides at nanogram levels is reported using resin column and sorption, and desorption followed by N-P gas-liquid chromatography (GLC) analysis. The carbamates were extracted from natural water by percolation through a column of Amberlite XAD-2, followed by elution with ethyl acetate. The carbamate residues were directly analyzed by GLC with a Tracor Model 702 N-P detector.
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